Hybrid magnetic materials based on polyethylene containing Co and Ni nanoparticles

Alexander Yu. Vasil’kov, Alexander V. Budnikov, Alexander V. Naumkin

Article ID: 742
Vol 3, Issue 1, 2020

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Abstract


New hybrid magnetic materials based on HDPE filled with Со and Ni nanoparticles have been prepared via the metal vapor synthesis. Properties of the metal-polymer composites have been elucidated as a function of MVS parameters and metal nature. The Faraday method has been applied to characterize the magnetic properties of the systems. The microstructure of the samples has been studied with a number of X-ray and synchrotron techniques, including XRD, EXAFS and SAXS. Core-level and valence band spectra were measured by XPS. The peak at binding energy of 282.8 eV characteristic of C-Ni bond was recorded in the C 1s spectrum. It was shown that properties of nanocomposite materials with similar compositions are determined both by the synthesis conditions and post-synthesis factors.


Keywords


Hybrid Material; Magnetic Properties; HDPE; Cobalt; Nickel; Nanoparticles; Metal Vapor Synthesis; XPS

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References


1. Vasil’kov AY, Migulin DA, Naumkin AV, et al. Preparation of novel hybrid materials based on core-shell polyorganosilsesquioxanes modified with iron nanoparticles. Mendeleev Communications 2016; 26(3): 187–190.

2. Rubina MS, Kamitov EE, Zubavichus YV, et al. Collagen-chitosan scaffold modified with Au and Ag nanoparticles: Synthesis and structure. Applied Surface Science 2016; 366: 365–371.

3. Tsodikov MV, Ellert OG, Nikolaev SA, et al. The role of nanosized nickel particles in microwave-assisted dry reforming of lignin. Chemical Engineering Journal 2017; 309: 628–637.

4. Rubina MS, Vasil’kov AY, Naumkin AV, et al. Synthesis and characterization of chitosan–copper nanocomposites and their fungicidal activity against two sclerotia-forming plant pathogenic fungi. Journal of Nanostructure in Chemistry 2017; 7: 249–258.

5. Selwood PW. Chemisorption and magnetization. New York: Academic Press; 1975. p. 164.

6. Chernyshov AA, Veligzhanin AA, Zubavichus YV. Structural materials science end-station at the Kurchatov Synchrotron Radiation Source: Recent instrumentation upgrades and experimental results. Nuclear Instruments & Methods in Physics Research 2009; 603(1-2): 95–98.

7. Davis SC, Severson SJ, Klabunde KJ. Clustering of metal atoms in organic media. 8. Low-temperature cleavage of alkanes by small nickel particles resulting in stable nickel-organic composites with unusual magnetic and chemical properties. Journal of American Chemical Society 1981; 103(11): 3024–3029.

8. Naumkin AV, Vasil’kov AY, Volkov IO, et al. X-ray photoelectron spectra and structure of composites prepared via deposition of Au, Ni, and Au + Ni nanoparticles on SiO2 from colloidal solutions in triethylamine. Inorganic Materials 2007; 43(4): 381–385.

9. Vasil’kov AY, Nikolaev SA, Smirnov VV, et al. An XPS study of the synergetic effect of gold and nickel supported on SiO2 in the catalytic isomerization of allylbenzene. Mendeleev Communications 2007; 17(5): 268–270.

10. Lian K, Thorpe SJ, Kirk DW. Electrochemical and surface characterization of electrocatalytically active amorphous Ni-Co alloys. Electrochimica Acta 1992; 37(11): 2029–2041.

11. Venezia AM, Bertoncello R, Deganello G. X-ray photoelectron spectroscopy investigation of pumice-supported nickel catalysts. Surface & Interface Analysis 1995; 23(4): 239–247.

12. Workie B, Kounaves SP, Aksu ML, et al. Electrodeposition of metal alloy and mixed oxide films using a single-precursor tetranuclear copper-nickel complex. Journal of The Electrochemical Society 1995; 142(10): 3357–3365.

13. Bianchi CL, Cattania MG, Villa P. XPS characterization of Ni and Mo oxides before and after “in situ” treatments. Applied Surface Science 1993; 70-71(93): 211–216.

14. McIntyre NS, Chan TC, Chen C. Characterization of oxide structures formed on nickel-chromium alloy during low pressure oxidation at 500-600℃. Oxidation of Metals 1990; 33(5-6): 457–479.

15. Mansour AN. Characterization of NiO by XPS. Surface Science Spectra 1994; 3(3): 239–246.

16. Lian KK, Kirk DW, Thorpe SJ. Investigation of a “Two-State” Tafel Phenomenon for the oxygen evolution reaction on an amorphous NiCo alloy. Journal of The Electrochemical Society 1995; 142(11): 3704–3712.

17. Mansour AN, Melendres CA. Characterization of α-Ni(OH)2 by XPS. Surface Science Spectra 1994; 3(3): 255–262.

18. Mansour AN, Melendres CA. Characterization of Ni2O3⋅6H2O by XPS. Surface Science Spectra 1994; 3(3): 263–270.

19. Mansour AN, Melendres CA. Characterization of electrochemically prepared γ-NiOOH by XPS. Surface Science Spectra 1994; 3(3): 271–278.

20. Mansour AN, Melendres CA. Characterization of slightly hydrated Ni(OH)2 by XPS. Surface Science Spectra 1994; 3(3): 247–254.

21. Mansour AN. Characterization of β-Ni(OH)2 by XPS. Surface Science Spectra 1994; 3(3): 239–246.

22. Chen X, Chen X, Zhang F, et al. One-pot hydrothermal synthesis of reduced graphene oxide/carbon nanotube/α-Ni(OH)2 composites for high performance electrochemical supercapacitor. Journal of Power Sources 2013; 243: 555–561.

23. Naumkin AV, Kraut-Vass A, Gaarenstroom SW, et al. NIST X-ray photoelectron spectroscopy database [Internet]. Version 4.1. Gaithersburg: National Institute of Standards and Technology; [created 2000 June 6; updated 2012 Spe 15]. Available from: http://srdata.nist.gov/xps/.

24. Payne BP, Biesinger MC, McIntyre NS. Use of oxygen/nickel ratios in the XPS characterisation of oxide phases on nickel metal and nickel alloy surfaces. Journal of Electron Spectroscopy And Related Phenomena 2012; 185(5-7): 159–166.

25. Payne BP, Biesinger MC, McIntyre NS. The study of polycrystalline nickel metal oxidation by water vapour. Journal of Electron Spectroscopy & Related Phenomena 2009; 175(1-3): 55–65.

26. Biesinger MC, Lau LWM, Gerson AR, et al. The role of the Auger parameter in XPS studies of nickel metal, halides and oxides. Physical Chemistry Chemical Physics 2012; 14(7): 2434–2442.

27. Tanuma S, Powell CJ, Penn DR. Calculations of electron inelastic mean free paths. IX. Data for 41 elemental solids over the 50 eV to 30 keV range. Surface and Interface Analysis 2011; 43(3): 689–713.

28. Powell CJ, Jablonski A. NIST electron inelastic-mean-free-path database 71 [Internet]. Version 1.1. Gaithersburg: National Institute of Standards and Technology; [created 2000 June 15; updated 2017 Feb 17]. Available from: https://www.nist. gov/publications/nist-electron-inelastic-mean-free-path-database-71-version-11

29. Henderson MA. The interaction of water with solid surfaces: fundamental aspects revisited. Surface Science Reports 2002; 46(1): 1–308.

30. Moulder JF, Stickle WF, Sobol PE, et al. Handbook of X-ray photoelectron spectroscopy: a reference book of standard spectra for identification and interpretation of XPS data. In: Chastain J (editor). Eden Prairie, Minnesota: Physical Electronics Division, Perkin-Elmer Corporation; 1992. p. 261.




DOI: https://doi.org/10.24294/can.v3i1.742

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