Preparation and characterization of magnetic graphene oxide nanocomposite (GO-Fe3O4) for removal of strontium and cesium from aqueous solutions
Vol 4, Issue 1, 2021
VIEWS - 2037 (Abstract) 2247 (PDF)
Abstract
Magnetic graphene oxide nanocomposites (M-GO) were successfully synthesized by partial reduction co-precipitation method and used for removal of Sr(II) and Cs(I) ions from aqueous solutions. The structures and properties of the M-GO was investigated by X-ray diffraction, Fourier transformed infrared spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy, scanning electron microscopy, vibrating sample magnetometer (VSM) and N2-BET measurements. It is found that M-GO has 2.103 mg/g and 142.070 mg/g adsorption capacities for Sr(II) and Cs(I) ions, respectively. The adsorption isotherm matches well with the Freundlich for Sr(II) and Dubinin–Radushkevich model for Cs(I) and kinetic analysis suggests that the adsorption process is pseudo-second-ordered.
Keywords
Full Text:
PDFReferences
1. Japan’s Challenges Towards Recovery. Ministry of Economy, Trade and Industry [Internet]. [cited March 2012]. Available from: http://www.meti.go.jp/english/earthquake/nuclear/japan-challenges/pdf/japan-challenges_full.pdf.
2. IAEA Briefing on Fukushima Nuclear Accident [cited 13 April 2011]. Available from: https://www.iaea.org/newscenter/news/fukushima-nuclear-accident-update-log-17.
3. Tangestani F, Mallah MH, Rashidi A, Habibzadeh R. Adsorption of Cesium, Strontium, and Rubidium radionuclides in the Magmolecular process: The influence of important factors. Advances in Environmental Technology 2017; 3: 139–49.
4. Anzai, K, Ban N, Ozawa T, et al. Fukushima Daiichi Nuclear Power Plant accident: Facts, environmental contamination, possible biological effects, and countermeasures. Journal of Clinical Biochemistry & Nutrition 2012; 50(1): 2–8.
5. Yusan S, Gok C, Erenturk S, et al. Adsorptive removal of thorium (IV) using calcined and flux calcined diatomite from Turkey: Evaluation of equilibrium, kinetic and thermodynamic data. Applied Clay Science 2012; 67: 106–116.
6. Yusan SD, Akyil S. Sorption of uranium (VI) from aqueous solutions by akaganeite. Journal of Hazardous Materials2008; 160(2-3): 388–395.
7. Yusan S, Bampaiti A, Erenturk S, et al. Sorption of Th (IV) onto ZnO nanoparticles and diatomite-supported ZnO nanocomposite: Kinetics, mechanism and activation parameters. Radiochimica Acta 2016; 104 (9): 635–647.
8. Gok C. Neodymium and samarium recovery by magnetic nano-hydroxyapatite. Journal of Radioanalytical and Nuclear Chemistry 2014; 301(3) :641–651.
9. Tayyebi A, Outokesh M, Moradi S, et al. Synthesis and characterization of ultrasound assisted “graphene oxide–magnetite” hybrid, and investigation of its adsorption properties for Sr(II) and Co(II) ions. Applied Surface Science 2015; 353: 350–362.
10. Yang H, Li H, Zhai J, et al. Magnetic prussian blue/graphene oxide nanocomposites caged in calcium alginate microbeads for elimination of cesium ions from water and soil. Chemical Engineering Journal 2014; 246: 10–19.
11. Jolivet J-P, Chanéac C, Tronc E. Iron oxide chemistry. From molecular clusters to extended solid networks. Cheminform 2004; 35(18): 481–483.
12. Chen S, Brown L, Levendorf M, et al. Oxidation resistance of graphene-coated Cu and Cu/Ni alloy. ACS Nano 2011; 5(2): 1321–1327.
13. Zhang Y, Chen B, Zhang L, et al. Controlled assembly of Fe3O4 magnetic nanoparticles on graphene oxide. Nanoscale 2011; 3: 1446–1450.
14. Yao Y, Miao S, Liu S, et al. Synthesis, characterization, and adsorption properties of magnetic Fe3O4@graphene nanocomposite. Chemical Engineering Journal 2012; 184: 326–332.
15. Yusan S, Korzhynbayeva K, Aytas S, et al. Preparation and investigation of structural properties of magnetic diatomite nanocomposites formed with different iron content . Journal of Alloys & Compounds 2014; 608: 8–13.
16. El-din TAS, Elzatahry AA, Aldhayan DM, et al. Synthesis and characterization of magnetite zeolite nano composite. International Journal of Electrochemical Science 2011; 6: 6177–6183.
17. Chen L, Xu J, Hu J. Removal of U(VI) from aqueous solutions by using attapulgite/iron oxide magnetic nanocomposites. Journal of Radioanalytical & Nuclear Chemistry 2013; 297(1): 97–105.
18. Nodeh HR, Ibrahim WAW, Ali I, et al. Development of magnetic graphene oxide adsorbent for the removal and preconcentration of As(III) and As(V) species from environmental water samples. Environmental Science and Pollution Research 2016; 23: 9759–773.
19. Guo J, Wang R, Tjiu WW, et al. Synthesis of Fe nanoparticles@graphene composites for environmental applications. Journal of Hazardous Materials 2012; 225-226: 63–73.
20. Qin Y, Long M, Tan B, et al. RhB adsorption performance of magnetic adsorbent Fe3O4/RGO composite and its regeneration through a Fenton-like reaction. Nano-Micro Letters 2014; 6(2): 125–135.
21. Lujaniene G, Semcuk S, Lecinskyte A, et al. Magnetic graphene oxide based nano-composites for removal of radionuclides and metals from contaminated solutions. Journal of Environmental Radioactivity 2017; 166(1): 166–174.
22. Dorniani D, Bin Hussein MZ, Kura AU, et al. Preparation of Fe3O4 magnetic nanoparticles coated with gallic acid for drug delivery. International Journal of Nanomedicine 2012; 7: 5745–5756.
23. Cheng, G, Yu, X, Zhou M, et al. Preparation of magnetic graphene composites with hierarchical structure for selective capture of phosphopeptides. Journal of Materials Chemistry B 2014; 2(29): 4711–4719.
24. Hur J. Shin J, Yoo J, Seo Y-S. Competitive adsorption of metals onto magnetic graphene oxide: Comparison with other carbonaceous adsorbents. The Scientific World Journal 2015: 836287.
25. Kakutani Y, Weerachawanasak P, Hirata Y, et al. Highly effective K-Merlinoite adsorbent for removal of Cs+ and Sr2+ in aqueous solution. RSC Advances 2017; 7: 30919–30928.
26. Khambhaty Y, Mody K, Basha S, et al. Kinetics, equilibrium and thermodynamic studies on biosorption of hexavalent chromium by dead fungal biomass of marine Aspergillus niger. Chemical Engineering Journal 2009; 145: 489–495.
27. Khani MH. Statistical analysis and isotherm study of uranium biosorption by Padina sp. algae biomass. Environmental Science & Pollution Research 2011; 18: 790–799.
28. Gok C, Aytas S. Recovery of thorium by high-capacity biopolymeric sorbent. Separation Science and Technology 2013;48(14): 2115–2124.
29. Langmuir I. The adsorption of gases on plane surfaces of glass, mica and platinum. Journal of Chemical Physics 2015; 40(9): 1361–1403.
30. Freundlich H. Adsorption in solution. Journal of Physical Chemistry 1906; 57: 384–410.
31. Dubinin MM. The potential theory of adsorption of gases and vapors for adsorbents with energet-ically non-uniform surface. Chemical Reviews 1960; 60: 235–266.
32. Temkin MJ, Pyzhev V. Recent modifications to Langmuir isotherms. Acta Physiochim 1940; 12: 217–222.
33. Flory PJ. Thermodynamics of high polymer solutions. Journal of Chemical Physics 1942; 10: 51–62.
34. Huggins ML. Some properties of solutions of long-chain compounds. Journal of Chemical Physics 1942; 10: 151–158.
35. Bruanuer S, Emmett PH, Teller E. Adsorption of gases in multimolecular layers. Journal of the American Chemical Society 1938; 60: 309–316.
36. Foo KY, Hameed BH. Insights into the modeling of adsorption isotherm systems. Chemical Engineering Journal 2010; 156: 2–10.
37. Jain AK, Gupta VK, Bhatnagar A, et al. Utilization of industrial waste products as adsorbents for the removal of dyes. Journal of Hazardous Materials 2003; B101: 31–42.
38. Lagergren S. Zur theorie der sogenannten adsorption geloster stoffe. Kungliga Svenska Vetnskap-sakademiens. Handlingar 1898; 24(4): 1–39.
39. Ho YS, Mckay G. The kinetics of sorption of basic dyes from aqueous solution by sphagnum moss peat. The Canadian Journal of Chemical Engneering 1998; 76: 822–827.
40. Liang S, Guo X, Feng N, et al. Isotherms, kinetics and thermodynamic studies of adsorption of Cu2+ from aqueous solutions by Mg2+/K+ type orange peel adsorbents. Journal of Materials Chemistry 2010; 174: 756–762.
41. Almeida CAP, Debacher NA, Downs AJ, et al. Removal of methylene blue from colored effluents by adsorption on montmorillonite clay. Journal of Colloid and Interface Science 2009; 332(1): 46–53.
DOI: https://doi.org/10.24294/can.v4i1.1291
Refbacks
- There are currently no refbacks.
Copyright (c) 2021 Sule Aytas, Sabriye Yusan, Senol Sert, Cem Gok
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
This site is licensed under a Creative Commons Attribution 4.0 International License.