Roentgenographic investigation of solid-phase equilibria in the PbSe-AgSbSe2 system

Mansimova Shabnam Hamlet, Orujlu Elnur Najaf, Babanly Mahammad Baba

Article ID: 586
Vol 2, Issue 2, 2019

VIEWS - 756 (Abstract) 139 (PDF)

Abstract


The solid-phase equilibria in the 2PbSe-AgSbSe2 system were studied by using the powder X-ray diffraction method.  It is established that the system is characterized by the formation of ~60 mol% solid solutions basedon AgSbSe2.Solubility based on PbSe is about 3mol%. The cubic lattice parameters of solid solutions are defined.


Full Text:

PDF


References


1. Applications of Chalcogenides: S, Se, and Te, ed. by GurinderKaurAhluwalia, Springer, 2016.

2. Babanly M.B., Yusibov Y.A., AbishevV.T. Ternary Chalcogenide Based on Copper and Silver., BSU Publisher, 1993

3. Babanly M.B., Chulkov E.V., Aliev Z. S., Shevel’kov A.V., and Amiraslanov I. R. Phase diagrams in thematerials science of topological insulators based on metal chalcogenides. Russ. J. Inorg. Chem., 2017, 62 (13): 1703–1729

4. Shevelkov A.V. Chemical aspects of the design of thermoelectric materials. Russ. Chem. Rev., 2008, (77): 1-19

5. Horichok I., Ahiska R., Freik D., Nykyruy L., Mudry S., Matkivskiy O., and Semko T. Phase Content and Thermoelectric Properties of Optimized Thermoelectric Structures Based on the Ag-Pb-Sb-Te System. J. Electron. Mater., 2016, 45(3): 1576-1583

6. Kusz B., Miruszewski T., Bochentyn B., Łapin´ski M., and Karczewski J., Structure and Thermoelectric Properties of Te- Ag-Ge-Sb (TAGS) Materials Obtained by Reduction of Melted Oxide Substrates. J. Electron. Mater., 2016, 45(2): 1085-1093

7. Papagno M., Eremeev S., Fujii J., Aliev Z.S., Babanly M.B., Mahatha S., Vobornik I., Mamedov N., Pacile D., and Chulkov E., Multiple Coexisting Dirac Surface States in Three-Dimensional Topological Insulator PbBi6Te10. ACS Nano, 2016, 10(3): 3518-3524

8. Shvets I.A., Klimovskikh I.I., Aliev Z.S., Babanly M.B., Sánchez-Barriga J., Krivenkov M., Shikin A.M., and Chulkov E.V. Impact of stoichiometry and disorder on the electronic structure of the PbBi2Te4−xSex topological insulator. Phys. Rev. B, 2017, (96): 235124 -7

9. West A.R. Solid State Chemistry and its Applications, 2nd ed., Wiley, Hoboken, 2014

10. Babanly M.B., Yusibov Y.A., Babanly N.B.The EMF Method with Solid-State Electrolyte in the Thermodynamic Investigation of Ternary Copper and Silver Chalcogenides. Electromotive Force and Measurement in Several Systems. S.Kara, Ed., Intechweb.Org, 2011, p 57-78

11. Villars P., Prince A., Okamoto H. Handbook of Ternary Alloy Phase Diagrams (10 volume set). American Technical Publishers, 1995, 15000p.

12. Tomashik V., Feychuk P., Shcherbak L. Ternary alloys based on II-VI semiconductor compounds. Chernivtsi Books-XX1, 2010, 440 p.

13. Aliev I.I., Babanly K.N., and Babanly N.B., Solid Solutions in the Ag2Se-PbSe-Bi2Se3 System.Inorg. Mater., 2008, 44(11): 1179-1182

14. Babanly N.B., Aliev I.I., Babanly K.N., and YusibovYu.A. Phase Equilibria in the Ag2Te-PbTe-Bi2Te3 System. Russ. J. Inorg. Chem., 2011, 56(9): 1472-1477

15. Mashadiyeva L.F., KevserJ.O., Aliev I.I., Yusibov Y.A., Taghiyev D.B.,Aliev Z.S., Babanlı M.B. Phase Equilibria in the Ag2Te-SnTe-Sb2Te3system and thermodynamic properties of the (2SnTe)1-x(AgSbTe2)xsolid solution. Phase equilibria and diffusion, 2017, 38(5): 603-614

16. Mashadiyeva L.F., Kevser J.O., Aliev I.I., Yusibov Y.A., Taghiyev D.B., Aliev Z.S., Babanlı M.B. The Ag2Te-SnTe-Bi2Te3 system and thermodynamic properties of the (2SnTe)1-x(AgBiTe2)x solid solutions series.J.Alloys.Compd., 2017, 724: 641-648

17. DalvenR. A review of the semiconductor properties of PbTe, PbSe, PbS, and PbO. Infrared Phys., 1969 (9): 141-184

18. Geller S., Wernick J. H.Ternary semiconducting compounds witch sodium chloride-like structure: AgSbSe2, AgSbTe2, AgBiS2, AgBiSe2. ActaCryst., 1959, (12): 46-52.

19. Massalski T.B., Ed., Binary Alloy Phase Diagrams, 2nd ed., ASM International, Materials Park, 1990, p 3589

20. EmsleyJ.The elements, 3rd edition. Clarendon, OxfordUniversityPress, 1998.




DOI: https://doi.org/10.24294/ace.v1i4.586

Refbacks

  • There are currently no refbacks.


Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.