Roentgenographic investigation of solid-phase equilibria in the PbSe-AgSbSe2system

Babanly Mahammad Baba, Mansimova Shabnam Hamlet, OrujluElnur Najaf

Article ID: 586
Vol 2, Issue 2, 2019, Article identifier:

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Abstract


The solid-phase equilibria in the 2PbSe-AgSbSe2system were studied by using the powder X-ray diffraction method.  It is established that the system is characterized by the formation of ~60 mol% solid solutions basedon AgSbSe2.Solubility based on PbSe is about 3mol%. The cubic lattice parameters of solid solutions are defined.


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References


Applications of Chalcogenides: S, Se, and Te, ed. by GurinderKaurAhluwalia, Springer, 2016.

Babanly M.B., Yusibov Y.A., AbishevV.T. Ternary Chalcogenide Based on Copper and Silver., BSU Publisher, 1993

Babanly M.B., Chulkov E.V., Aliev Z. S., Shevel’kov A.V., and Amiraslanov I. R. Phase diagrams in thematerials science of topological insulators based on metal chalcogenides. Russ. J. Inorg. Chem., 2017, 62 (13): 1703–1729

Shevelkov A.V. Chemical aspects of the design of thermoelectric materials. Russ. Chem. Rev., 2008, (77): 1-19

Horichok I., Ahiska R., Freik D., Nykyruy L., Mudry S., Matkivskiy O., and Semko T. Phase Content and Thermoelectric Properties of Optimized Thermoelectric Structures Based on the Ag-Pb-Sb-Te System. J. Electron. Mater., 2016, 45(3): 1576-1583

Kusz B., Miruszewski T., Bochentyn B., Łapin´ski M., and Karczewski J., Structure and Thermoelectric Properties of Te- Ag-Ge-Sb (TAGS) Materials Obtained by Reduction of Melted Oxide Substrates. J. Electron. Mater., 2016, 45(2): 1085-1093

Papagno M., Eremeev S., Fujii J., Aliev Z.S., Babanly M.B., Mahatha S., Vobornik I., Mamedov N., Pacile D., and Chulkov E., Multiple Coexisting Dirac Surface States in Three-Dimensional Topological Insulator PbBi6Te10. ACS Nano, 2016, 10(3): 3518-3524

Shvets I.A., Klimovskikh I.I., Aliev Z.S., Babanly M.B., Sánchez-Barriga J., Krivenkov M., Shikin A.M., and Chulkov E.V. Impact of stoichiometry and disorder on the electronic structure of the PbBi2Te4−xSex topological insulator. Phys. Rev. B, 2017, (96): 235124 -7

West A.R. Solid State Chemistry and its Applications, 2nd ed., Wiley, Hoboken, 2014

Babanly M.B., Yusibov Y.A., Babanly N.B.The EMF Method with Solid-State Electrolyte in the Thermodynamic Investigation of Ternary Copper and Silver Chalcogenides. Electromotive Force and Measurement in Several Systems. S.Kara, Ed., Intechweb.Org, 2011, p 57-78

Villars P., Prince A., Okamoto H. Handbook of Ternary Alloy Phase Diagrams (10 volume set). American Technical Publishers, 1995, 15000p.

Tomashik V., Feychuk P., Shcherbak L. Ternary alloys based on II-VI semiconductor compounds. Chernivtsi Books-XX1, 2010, 440 p.

Aliev I.I., Babanly K.N., and Babanly N.B., Solid Solutions in the Ag2Se-PbSe-Bi2Se3 System.Inorg. Mater., 2008, 44(11): 1179-1182

Babanly N.B., Aliev I.I., Babanly K.N., and YusibovYu.A. Phase Equilibria in the Ag2Te-PbTe-Bi2Te3 System. Russ. J. Inorg. Chem., 2011, 56(9): 1472-1477

Mashadiyeva L.F., KevserJ.O., Aliev I.I., Yusibov Y.A., Taghiyev D.B.,Aliev Z.S., Babanlı M.B. Phase Equilibria in the Ag2Te-SnTe-Sb2Te3system and thermodynamic properties of the (2SnTe)1-x(AgSbTe2)xsolid solution. Phase equilibria and diffusion, 2017, 38(5): 603-614

Mashadiyeva L.F., Kevser J.O., Aliev I.I., Yusibov Y.A., Taghiyev D.B., Aliev Z.S., Babanlı M.B. The Ag2Te-SnTe-Bi2Te3 system and thermodynamic properties of the (2SnTe)1-x(AgBiTe2)x solid solutions series.J.Alloys.Compd., 2017, 724: 641-648

DalvenR. A review of the semiconductor properties of PbTe, PbSe, PbS, and PbO. Infrared Phys., 1969 (9): 141-184

Geller S., Wernick J. H.Ternary semiconducting compounds witch sodium chloride-like structure: AgSbSe2, AgSbTe2, AgBiS2, AgBiSe2. ActaCryst., 1959, (12): 46-52.

Massalski T.B., Ed., Binary Alloy Phase Diagrams, 2nd ed., ASM International, Materials Park, 1990, p 3589

EmsleyJ.The elements, 3rd edition. Clarendon, OxfordUniversityPress, 1998.




DOI: http://dx.doi.org/10.24294/ace.v1i4.586

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