Validation of Flory-Huggins model for phenol adsorption by Parthenium hysterophorus in a batch system

Zakia Latif1, Aliya Fazal2, Muhammad Aziz Choudhary1, Zahoor Ahmad1, Muhammad Aslam Mirza1

Article ID: 432
Vol 2, Issue 2, 2019

VIEWS - 646 (Abstract) 208 (PDF)

Abstract


Parthenium hysterophorus weed powder was studied as adsorbent for phenol adsorption from its aqueous standardized solution. The adsorption of pollutant was found improving with an increase of biomass dosage and contact time. The intraparticle diffusion of phenol onto adsorbent surface was identified to be the rate limiting step. Linear form of Flory-Huggins model revealed preeminence to Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich due to highest value of R2. The remediation process was figured out as a physisorption rather than a chemical one based on value of E (0.21KJ/mol). Active sites of sorbent surface identified by FT-IR were oxygen containing functional groups. Recent study proposes cost effective utilization of toxic allergent for treatment of toxic waste.


Keywords


Adsorption; Kinetic; Equilibrium; Active sites

Full Text:

PDF


References


1. Wake H. Oil refineries: A review of their ecological impacts on the aquatic environment. Estuarine, Coastal and

2. Shelf Science, 2005, 62(1–2): 131–140.

3. Kujawski W, Warzawski A, Ratajczak W, et al. Application of pervaporation and adsorption to the phenol removal

4. from wastewater. Separation & Purification Technology, 2004, 40(2): 123–132.

5. Srivastava VC, Swamy MM, Mall ID, et al. Adsorptive removal of phenol by bagasse fly ash and activated carbon.

6. Colloids & Surfaces A Physicochemical & Engineerimg Aspects, 2006, 272(1): 89–104.

7. Olafadehan OA, Aribike DS. Treatment of industrial wastewater effluent. Journal of Nigerian Society of Chemical

8. Engineers, 2000, 19: 50–53.

9. Radhika M, Palanivelu K. Adsorptive removal of chlorophenols from aqueous solution by low cost adsorbentKinetics

10. and isotherm analysis. Journal of Hazardous Materials, 2006, 138(1): 116–124.

11. Hameed BH, Rahman AA. Removal of phenol from aqueous solutions by adsorption onto activated carbon prepared

12. from biomass material. Journal of Hazardous Materials, 2008, 160(2): 576–581.

13. Aygun A, Karakas YS, Duman I. Production of granular activated carbon from fruit stones and nutshells and evalua

14. tion of their physical, chemical and adsorption properties. Microporous & Mesoporous Materials, 2003, 66(2): 189–

15.

16. Karunarathnea HDSS, Amarasinghea BMWPK. Fixed bed adsorption column studies for the removal of aqueous

17. phenol from activated carbon prepared from sugarcane bagasse. Energy Procedia, 2013, 34(40): 83–90.

18. Taha S, Cisse S, Dorange IG. Heavy metals removal by adsorption onto peanut husks carbon: Characterization kinet

19. ic study and modeling. Separation & Purification Technology, 2001, 24(3): 389–401.

20. Namasivayam C, Kavitha D. IR, XRD and SEM studies on the mechanism of adsorption of dyes and phenols by

21. coir pith carbon from aqueous phase. Microchemical Journal, 2006, 82(1): 43–48.

22. Shiundu PM, Mbui DN, Ndonye RM, et al. Adsorption and detection of some phenolic compounds by rice husk ash

23. of Kenyan origin. Journal of Environmental Monitoring Jem, 2002, 4(6): 978–984.

24.

25. Daizy R, Harminder B, Singh P, et al. Phytotoxic effect of Parthenium residues on the selected soil properties and

26. growth of chickpea and radish. Weed Biology and Management, 2002, 2(2): 73–78.

27. Louhi A, Hammadi A, Achouri A. Determination of some heavy metal pollutants in sediments of the Seybouse river

28. in Annaba, Algeria. Air, Soil and Water Research, 2012, 5(5): 91–101.

29. Elumalai S, Sakthivel R. GC-MS and FT-IR spectroscopic determination of Fattyacid Methyl Ester of 16 freshwater

30. Microalgae, isolated from cement industries of Tamil Nadu, India. J. Algal Biomass Utln, 2013, 4(1): 50–69.

31. Yu P, Block H, Niu Z. Rapid characterization of molecular chemistry, nutrient make-up and microlocation of internal

32. seed tissue. Journal of Synchrotron Radiation, 2007, 14(4): 382–390.

33. Wetzel DL, Eilert AJ, Pietrzak LN, et al. Ultraspatially-resolved synchrotron infrared microspectroscopy of plant

34. tissue. Cell Mol Biol (Noisy-le-grand), 1998, 44(1): 145–167.

35. Abdullah N, Suleiman F, Gerhauser H. Characterisation of oil palm empty fruit bunches for fuel application. Journal

36. of Physical Science, 2011, 22(1): 1–24.

37. Amir S, Hafidi M, Merlina G, et al. Elemental analysis, FTIR and 13C-NMR of humic acids from sewage sludge

38. composting. Agronomie, 2004, 24(1): 13–18.

39. Sugumaran P, Susan PV, Ravichandran P, et al. Production and characterization of activated carbon from banana

40. empty fruit bunch and Delonix regia fruit pod. Journal of Sustainable Energy and Environment, 2012, 3: 125–132.

41. Stavropoulos GG, Samaras P, Sakellaropoulos GP. Effect of activated carbons modification on porosity, surface

42. structure and phenol adsorption. Journal of Hazardous Materials, 2008, 151(2–3): 414–421.

43. Boudrahem F, Aissani-Benissad F, Soualah A. Kinetic and equilibrium study of the sorption of Lead(II) Ions from

44. aqueous phase by activated carbon. Arabian Journal for Science & Engineering, 2013, 38(8): 1939–1949.

45. Al-Anber ZA, Al-Anber M. Thermodynamics and kinetic studies of Iron(III) adsorption by olive cake in a batch

46. system. Journal of the Mexican Chemical Society, 2008, 52(2): 108–115.

47. Awala HA, El Jamal MM. Equilibrium and kinetics study of adsorption of some dyes onto Feldspar. Journal of the

48. University of Chemical Technology and Metallurgy, 2011, 46: 45–52.

49. Alzaydien SA, Manasreh W. Equilibrium, kinetic and thermodynamic studies on the adsorption of phenol onto activated

50. phosphate rock. International Journal of Physical Sciences, 2009, 4(4): 172–181.

51. Muthamilsevi P, Poonguzhali E, Karthikeyan R. Removal of phenol from aquous solution by adsorption. International

52. journal of advanced research in engineering and technology IJARET, 2012, 3: 280–288.

53. Sutherland C, Venkobachar C. A diffusion-chemisorption kinetic model for simulating biosorption using forest

54. macro-fungus, Fomes fasciatus, International Research Journal of Plant Science, 2010, 1: 107–117.

55. Juang R, Wu F, Tseng R. Mechanism of adsorption of dyes and phenols from water using activated carbons prepared

56. from Plum Kernels. Journal of Colloid and Interface Science, 2000, 227: 437–444.

57. Kumar D, Subbaiah VM, Reddy AS, et al. Biosorption of phenolic compounds from aqueous solutions onto Chitosan-Aabrus

58. Precatorius blended beads. J Chem Technol Biotechnol, 2009, 84: 972–981.

59. Annadurai G, Juang SR, Lee DJ. Use of Cellulose-based wastes for adsorption of dyes from aqueous solutions.

60. Journal of Hazardous Materials. 92, (2002)263-274.

61. Zhao X, Urano K, Ogasawara S. Adsorption of Polyethylene Glycol from Aqueous Solution on MontRillonite

62. Clays. Colloid and Polymer Science, 1989, 267: 899–906.

63. Theivarasu C, Mylsamy S. Removal of malachite green from aqueous solution by activated carbon developed from

64. Cocoa (Theobroma Cacao) Shell-A Kinetic and Equilibrium Studies. E-Journal of Chemistry, 2011, 8: 363–371.

65. Dada AO, Olalekan AP, Olatunya AM, et al. Freundlich, Temkin and Dubinin–Radushkevich isotherms studies of

66. equilibrium sorption of Zn2+ unto Phosphoric Acid modified rice husk. IOSR Journal of Applied Chemistry, 20112,

67. : 38–45.

68. Aikpokpodion PE, Osobamiro T, Atewolara-Odule OC, et al. Studies on adsorption mechanism and kinetics of

69. magnesium in selected cocoa growing soils in Nigeria. Journal of Chemical and Pharmaceutical Research, 2013, 5:

70. –1399.

71. Israel AA, Okon O, Umoren S, et al. Kinetic and equilibrium studies of adsorption of lead (ii) ions from aqueous

72. solution using coir dust (cocos nucifera l.) And it’s modified extract resins. The Holistic Approach to Environment,

73. , 34: 209–222.

74. Dabhade MA, Saidutta MB, Murthy DVR, Adsorption of phenol on granular activated carbon from nutrient medium:

75. Equilibrium and kinetic study. International Journal of Environmental Research, 2009, 3: 557–568.

76. Zheng H, Wang Y, Zheng Y, et al. Equilibrium, kinetic and thermodynamic studies on the sorption of 4-

77. hydroxyphenol on Cr-bentonite. Chemical Engineering Journal, 2008, 143: 117–123.




DOI: https://doi.org/10.24294/ace.v1i2.432

Refbacks

  • There are currently no refbacks.


Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.