Photocatalytic hydrogen production of Melon/Azodiphenylamine polymers

Jianhui Wang, Chengbo Fan, Yachao Zhai, Yuhao Tang, Haopeng Hou, Yaxin Zhu, Fengming Zhang

Article ID: 1353
Vol 4, Issue 2, 2021

VIEWS - 924 (Abstract) 214 (PDF)

Abstract


Hydrogen is one of the most attractive energy sources at present for its excellent properties, such as high energy density, clean and non-pollution energy. Photocatalytic hydrogen evolution is one of the ideal strategies to obtain hydrogen energy. This work aimed to improve the visible-light absorption ability of the structure similar to g-C3N4 by anchoring azo groups into the structure. By this, the photocatalytic hydrogen production rate of the resulting product was improved apparently. We use melamine as starting material to prepare Melon, which was further reacted with KOH, PCl5 and 4, 4-Diaminoazobenzene to get the target Melon/4, 4-Diaminoazobenzene polymer. The condition influencing on the reaction was investigated, such as reaction temperature, the ratio of reactants and concentration of KOH solution. The structure of the as-synthesized polymer was determined IR, XRD, SEM, TGA and EIS. At the same time, its photocatalytic property was investigated.

Keywords


Hydrogen Evolution; Melon; Photocatalytic; g-C3N4

Full Text:

PDF


References


1. Zhu Q, Xu Q. Liquid organic and inorganic chemical hydrides for high-capacity hydrogen storage. Energy and Environmental Science 2015; 8(2): 478–512.

2. Nasalevich MA, Becker R, Ramos-Fernandez EV, et al. Co@ NH2-MIL-125(Ti): Cobaloxime-derived metal-organic framework-based composite for light-driven H2 production. Energy and Environmental Science 2015; 8: 364–375.

3. Toyao T, Saito M, Horiuchi Y, et al. Efficient hydrogen production and photocatalytic reduction of nitrobenzene over a visible-light-responsive metal-organic framework photocatalyst. Catalysis Science & Technology 2013; 3: 2092–2096.

4. Yin S, Han J, Zhou T, et al. Recent progress in g-C3N4 based low cost photocatalytic system: Activity enhancement and emerging applications. Catalysis Science & Technology 2015; 5(12): 5048–5061.

5. Sun ZQ, Kim JH, Zhao Y, et al. Rational design of 3D dendritic TiO2 nanostructures with favorable architectures. Journal of the American Chemical Society 2011; 133(48): 19314–19317.

6. Wang G, Wang H, Li Y, et al. Hydrogen-treated TiO2 nanowire arrays for photoelectrochemical water splitting. Nano Letters 2011; 11(7): 3026–3033.

7. Morgan DL, Liu HW, Frost RL, et al. Implications of precursor chemistry on the alkaline hydrothermal synthesis of titania/titanate nanostructures. The Journal of Physical Chemistry C 2010; 114(1): 101–110.

8. Fang Z, Liu Y, Shen J, et al. Epitaxial growth of CdS nanoparticle on Bi2S3 nanowire and photocatalytic application of the heterostructure. The Journal of Physical Chemistry C 2011; 115: 13968–13976.

9. Burtch NC, Jasuja H, Walton KS. Water stability and adsorption in metal-organic frameworks. Chemical Reviews 2014; 114(20): 10575–10612.

10. Chen B, Xiang S, Qian G. Metal-organic frameworks with functional pores for recognition of small molecules. Accounts of Chemical Research 2010; 43: 1115–1124.

11. Hoang S, Guo SW, Mullins CB. Coincorporation of N and Ta into TiO2 nanowires for visible light driven photoelectrochemical water oxidation. The Journal of Physical Chemistry C 2012; 116(44): 23283–23290.

12. Li DS, Soberanis F, Fu J, et al. Growth mechanism of highly branched titanium dioxide nanowires via oriented attachment. Crystal Growth & Design 2013; 13: 422–428.




DOI: https://doi.org/10.24294/ace.v4i2.1353

Refbacks

  • There are currently no refbacks.


Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.