Analysis of chemical components and liquefaction process of eucalyptus globulus bark

Yongjun Liu, Hongzhou Shi, Yangmei Wang, Jing Wen

Article ID: 1347
Vol 4, Issue 2, 2021

VIEWS - 965 (Abstract) 223 (PDF)

Abstract


For 5-year-old Eucalyptus globulus, the optimal liquefaction bark process was explored by analyzing the chemical components of the bark and its liquefaction residue before and after the liquefaction. The results of chemical component determination showed that the contents of cellulose,hemicellulose and lignin of bark were 36.65%, 18.98%, and 45.37% respectively. The contents of benzene-alcohol extractives,hot-water extractives and 1% NaOH extractives were 10.30%, 7.15%, and 23.64% respectively. The content of ash accounted for 7.49%. The liquefaction process showed that the catalytic effect of concentrated sulfuric acid was better than concentrated phosphoric acid. The optimum liquefaction parameters were catalytic of 3% concentrated sulfuric acid,temperature of 160 ℃ and the liquid-solid ratio of 5:1. The liquefaction rate was 82.8% under the above optimal conditions. Compared with raw materials, the cellulose content, hemicellulose content, and lignin content of liquefaction residue reduced by 17.90%, 9.19%, and 15.99%, respectively.

Keywords


Eucalyptus; Bark; Chemical Composition; Liquefaction

Full Text:

PDF


References


1. Xiong J. Myrtle family. In: Flora of Sichuan (v8). Chengdu: Sichuan People’s Publishing House; 1990. p. 305.

2. Yang X, Feng L, Hua W. Way out and prospect of development and use of energy sources in China (in Chinese). Frontier Science 2012; (2): 22-29.

3. Fu S, Ma L, Li, W. Studies on liquefaction of bamboo and properties of liquefied-bamboo adhesives (in Chinese). Chemistry and Industry of Forest Products 2004; 24(3): 42-46.

4. Kobayashi M, Tukamoto K, Tomita B. Application of liquefied wood to a new resin system-synthesis and properties of liquefied wood epoxy resins. Holzforschung 2000; 54(1): 93-97.

5. Fu S, Yu R, Du B, et al. Liquefaction of bamboo and preparation of liquefied bamboo adhesive (in Chinese). China Forest Products Industry 2004; 31(3): 35-38.

6. Zhang Y, Chi Q, Sun Y, et al. Research of liquefaction of wood and its utilization for polyurethane adhesives (in Chinese). Chemistry and Industry of Forest Products 2007; 27(5): 73-77.

7. Lin L, Yao Y, Yoshioka M, et al. Preparation and properties of phenolated wood phenol formaldehyde cocondensed resin. Journal of Applied Polymer Science 1995; 58(8): 1297-1304.

8. Alma M, Yao Y, Yoshioka M, et al. The preparation and flow properties of HCl catalyzed phenolated wood and its blends with commercial novolak resin. Holzforschung 1996; 50(1): 85-90.

9. Lee SH, Yoshioka M, Shiraishi N. Resol-type phenolic resin from liquefied phenolated wood and its application to phenolic foam (in Chinese). Journal of Applied Polymer Science 2002; 84(3): 468-472.

10. Wang C, Cui L, Zhang J. Development status and research prospect of wood liquefaction (in Chinese). Forestry Science & Technology 2007; 32(3): 42-43.

11. Jie S, Zhang Q, Zhao G. Process of wood liquefaction and its application in preparation of polymer materials (in Chinese). Biomass Chemical Engineering 2005; (6): 43-49.




DOI: https://doi.org/10.24294/ace.v4i2.1347

Refbacks

  • There are currently no refbacks.


Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.