Residue dissipation kinetics, safety evaluation and decontamination of Deltamethrin in tomato and the soil
Vol 7, Issue 1, 2024
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Abstract
Tomato powdery mildew, fruit rot, and twig blight are all managed with Deltamethrin. Its residues could still be present in the crops, posing a health risk. The pesticide residue analysis, dissipation rate, and safety assessments were thus examined in green tomatoes. The analytical method for residue analysis was validated according to international standards. Tomato fruits and soil were used to study the dissipation of Deltamethrin 100 EC (11% w/w) at 12.5 g a.i ha−1 for the recommended dose (RD) and 25.0 g a.i ha−1 for the double of the recommended dose (DD). Ethyl acetate was used to extract residues from tomato fruit, and PSA and magnesium sulphate were used for cleanup.The fruits had recoveries ranging from 83% to 93% and the soil sample from 81.67% to 89.6%, with the limit of detection (LOQ) estimated at 0.01 mg kg−1. The matrix effect (ME) was calculated to be less than 20% for the tomato fruits and the soil.Half-lives for RD and DD were 1.95 and 1.84 days, respectively. All sampling days for both doses had dietary exposures of residues below the maximum permissible intake (MPI) of 0.16 mg person−1 day−1. The most effective method of decontaminating tomato residue containing Deltamethrin is blanching.
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1. Khanam UKS, Hossain M, Ahmed N, et al. Varietal Screening of Tomato to Tomato Fruit Borer, Helicoverpa armigera (Hub.) and Associated Tomato Plant Characters. Pakistan Journal of Biological Sciences. 2003; 6(4): 413-421. doi: 10.3923/pjbs.2003.413.421
2. Razdan MK. Genetic Improvement of Solanaceous Crops Volume 2. Published online January 12, 2006. doi: 10.1201/b10744
3. Tiwari A, Afroz SB, Kumar V. Market vulnerabilities and potential of horticulture crops in India: with special reference to top crops. Ind J Agril Mktg. 2021.
4. NHB. Indian Horticulture Data Base, National Horticulture Board Ministry of Agriculture and Farmers Welfare India 490. 2018.
5. Pandey AK, Namgyal D, Mehdi M, et al. A case study major insect pest associated with different vegetable crops in cold arid region Ladakh of Jammu and Kashmir. J Entomol Res. 2006; 30: 69-174.
6. Dhandapani N, Umeshchandra SR, Murugan M. Biointensive pest management (BIPM) in major vegetable crops An Indian perspective. Food Agric Environ. 2003; 1: 333-339.
7. Meena LK, Raju SVS. Bio efficacy of newer insecticides against tomato fruit borer, Helicoverpa armigera (Hubner) on tomato (Lycopersicon esculentum) mill under field conditions. Int J Life Sci. 2014; 347-350.
8. Divekar PA, Narayana S, Divekar BA, et al. Plant secondary metabolites as defence tools against herbivores for sustainable crop protection. Int J mol Sci. 2022; 23: 2690. doi: 10.3390/ ijms23052690.
9. Divekar PA, Rani V, Majumder S, et al. Protease Inhibitors: An Induced Plant Defense Mechanism Against Herbivores. Journal of Plant Growth Regulation. 2022; 42(10): 6057-6073. doi: 10.1007/s00344-022-10767-2
10. Majumder S, Pandey J, Divekar PA, et al. Dissipation kinetics, food safety evaluation and decontamination of chlorantraniliprole in cowpea. Journal of Environmental Science and Health, Part B. 2023; 58(5): 389-398. doi: 10.1080/03601234.2023.2216125
11. Sreekanth M, Lakshmi MSM, Rao YK. Efficacy and economics of certain new generation novel insecticides against legume pod borer Marucavitrata (Geyer) on pigeon pea (Cajanus cajan L.). J App Biol Biotech. 2015; 3: 7-10.
12. Majumder S, Rani AT, Divekar PA, et al. Field bioefficacy and residue dynamics of chlorantraniliprole (18.50% sc) in okra (Abelmoschus esculentus). The Indian Journal of Agricultural Sciences. 2023; 93(3). doi: 10.56093/ijas.v93i3.132324
13. Faqiri M, Kumar A. Management of tomato fruit borer Helicoverpa armigera (Hubner) by chemical insecticides and neem products. Int Multidiscip Res J. 2016; 3: 82-85.
14. Kumari B, Madan VK, Kumar R, et al. Monitoring of seasonal vegetables for pesticide residues. Environ Monitor Assess. 2002; 74: 263-270. doi: 10.1023/A:1014248827898
15. Dukare A, Paul S, Mhatre P, et al. Biological Disease Control Agents in Organic Crop Production System. Pesticide Contamination in Freshwater and Soil Environs. Published online June 7, 2021: 255-282. doi: 10.1201/9781003104957-10
16. Central Insecticide Board & Registration Committee N.H.-IV, Major uses of pesticides. Available online: https://ppqs.gov.in/sites/default/files/approved_use_of_insecticides.pdf (accessed on 7 December 2023).
17. Majumder S, Mandal S, Majumder B, et al. A liquid chromatographic method for determination of acetamiprid and buprofezin residues and their dissipation kinetics in paddy matrices and soil. Environmental Science and Pollution Research. 2021; 29(1): 1401-1412. doi: 10.1007/s11356-021-15784-4
18. European Commission. Method validation procedures for pesticide residues analysis 688 in food and feed. Sante/12830/2020. Available online: https://food.ec.europa.eu/system/files/2023-04/pesticides_mrl_guidelines_2020-12830.pdf (accessed on 8 December 2023).
19. Hoskins WM. Mathematical treatment of the rate of loss of pesticide residues. FAO Plant Prot Bull. 1961; 9: 163-168.
20. Bhuvaneswari K, Karthik P, Selvi C, et al. Impact of decontamination processes on the reduction of pesticide residues in green chilli. Indian Journal of Entomology. Published online April 3, 2023. doi: 10.55446/ije.2023.727
21. Majumder S, Singh S, Divekar PA, et al. Residue dissipation kinetics, safety evaluation and decontamination of hexaconazole in green chilli. International Journal of Environmental Analytical Chemistry. Published online May 29, 2022: 1-13. doi: 10.1080/03067319.2022.2078201
22. Sharma KK, Tripathy V, Rao CS, et al. Persistence, dissipation, and risk assessment of a combination formulation of trifloxystrobin and tebuconazole fungicides in/on tomato. Regulatory Toxicology and Pharmacology. 2019; 108: 104471. doi: 10.1016/j.yrtph.2019.104471
23. Paramasivam M, Chandrasekaran S. Persistence behaviour of deltamethrin on tea and its transfer from processed tea to infusion. Chemosphere. 2014; 111: 291-295. doi: 10.1016/j.chemosphere.2014.03.111
24. Majumder S, Verma CK, Rani V, et al. Residue dynamics and food safety evaluation of fungicide kresoxim-methyl in green chilli (Capsicum annum L.). International Journal of Environmental Analytical Chemistry. 2020; 102(19): 7433-7443. doi: 10.1080/03067319.2020.1830986
25. Rahman MdM, Jang J, Park JH, et al. Determination of kresoxim-methyl and its thermolabile metabolites in pear utilizing pepper leaf matrix as a protectant using gas chromatography. Journal of Advanced Research. 2014; 5(3): 329-335. doi: 10.1016/j.jare.2013.05.003
DOI: https://doi.org/10.24294/th.v7i1.3985
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