Modeling and simulation of liquid metal battery (LMB) materials development using statistical package for social sciences (S.P.S.S.)

Abstract

There are a number of input parameters that are considered in relation to the stimulatory possibility of constructing a Liquid Metal Battery (LMB). This paper talks about the modeling approach possible for use in LMB research work. Equivalent Circuit Modeling (E.C.M.) is the most common method used to analyze input data or parameters. In analyzing some of the basic elements, such as electrical capacitance, electrical resistance, open circuit voltage, terminal voltage, temperature, time response, time constants, State of Charge (SOC), etc. The cell impedance could be calculated by predicting the system elements that would play key roles in the determination of the parameter identification method for the battery’s Equivalent Circuit Model. Secondly, each element in the model has a known behaviour, which mainly depends on the element type and the values of the parameters that characterize that element. In EIS software, the Graphical Model Editor could be used to build an equivalent circuit model, or the befitting model could be carefully and properly selected. Thirdly, in fitting the Equivalent Circuit Model (ECM) to the initial data or parameters, one must take note that the parameters are strongly dependent on temperature, heat, and losses. Such are: the Open Circuit Voltage (OCV), which is strongly dependent on the temperature, the loss processes depend on temperature; losses produced by the loss processes are dissipated as heat energy; the heat generated or consumed by the electrochemical reactions during normal operation has a defined temperature; and a system with a defined temperature window with safe, stable, and efficient operation is achievable. At the end of this research, the simulation of Lithium (Li) and Cadmium (Cd) was found to be in the proportion of 67:33, which is used to determine the strength of the reactivity of the metals. From Figure 5, the Bi and Li chemical compositions of the metals in the graph are equal to 49 for Li and 51 for Bismuth, which makes the overall reactivity very high, which could be used for LMB development.