Mechanical properties of spinel (MgCr2O4) phase containing alumino-silicate glass-ceramic

Mrinmoy Garai, Arianit A. Reka, Shibayan Roy

Article ID: 6046
Vol 7, Issue 2, 2024

VIEWS - 616 (Abstract) 86 (PDF)

Abstract


This research study explores the addition of chromium (Cr6+) ions as a nucleating agent in the alumino-silicate-glass (ASG) system (i.e., Al2O3-SiO2-MgO-B2O3-K2O-F). The important feature of this study is the induction of nucleation/crystallization in the base glass matrix on addition of Cr6+ content under annealing heat treatment (600 ± 10 °C) only. The melt-quenched glass is found to be amorphous, which in the presence of Cr6+ ions became crystalline with a predominant crystalline phase, Spinel (MgCr2O4). Microstructural experiment revealed the development of 200–500 nm crystallite particles in Cr6+-doped glass-ceramic matrix, and such type microstructure governed the mechanical properties. The machinability of the Cr-doped glass-ceramic was thereby higher compared to base alumino-silicate glass (ASG). From the nano-indentation experiment, the Young’s modulus was estimated 25(±10) GPa for base glass and increased to 894(±21) GPa for Cr-doped glass ceramics. Similarly, the microhardness for the base glass was 0.6(±0.5) GPa (nano-indentation measurements) and 3.63(±0.18) GPa (micro-indentation measurements). And that found increased to 8.4(±2.3) (nano-indentation measurements) and 3.94(±0.20) GPa (micro-indentation measurements) for Cr-containing glass ceramic.


Keywords


alumino-silicate glass; nucleation; microstructure; microhardness

Full Text:

PDF


References


1. Zarabi Golkhatmi S, Asghar MI, Lund PD. A review on solid oxide fuel cell durability: Latest progress, mechanisms, and study tools. Renewable and Sustainable Energy Reviews. 2022; 161: 112339. doi: 10.1016/j.rser.2022.112339

2. Beall GH. Milestones in Glass‐Ceramics: A Personal Perspective. International Journal of Applied Glass Science. 2014; 5(2): 93-103. doi: 10.1111/ijag.12063

3. Lin C, Liu J, Han L, et al. Study on the structure, thermal and optical properties in Cr2O3-incorporated MgO-Al2O3-SiO2-B2O3 glass. Journal of Non-Crystalline Solids. 2018; 500: 235-242. doi: 10.1016/j.jnoncrysol.2018.08.004

4. Garai M, Karmakar B, Roy S. Cr6+ Controlled Nucleation in SiO2-MgO-Al2O3-K2O-B2O3-F Glass Sealant (SOFC). Frontiers in Materials. 2020; 7: 57. doi: 10.3389/fmats.2020.00057

5. Pingale SS, Patil SF, Vinod MP, et al. Mechanism of humidity sensing of Ti-doped MgCr2O4 ceramics. Materials Chemistry and Physics. 1996; 46(1): 72-76.

6. Bremm S, Dölling S, Becker W, et al. A methodological contribution to failure prediction of glass ceramics sealings in high-temperature solid oxide fuel cell stacks. Journal of Power Sources. 2021; 507: 230301. doi: 10.1016/j.jpowsour.2021.230301

7. Sun, T, Chi Z, Feng Z, et al. Mixed CaO/MgO effect on microstructure, mechanical properties and crystallization behaviour of Li2O-Al2O3-SiO2-ZrO2-P2O5 glass. Journal of Non-Crystalline Solids. 2023; 616: 122457. doi: doi.org/10.1016/j.jnoncrysol.2023.122457

8. Aktas B, Yalcin S, Dogru K, et al. Structural and radiation shielding properties of chromium oxide doped borosilicate glass. Radiation Physics and Chemistry. 2019; 156: 144-149. doi: 10.1016/j.radphyschem.2018.11.012

9. Timurkutluk C, Toruntay F, Onbilgin S, et al. Development of ceramic fiber reinforced glass ceramic sealants for microtubular solid oxide fuel cells. Ceramics International. 2022; 48(11): 15703-15710. doi: 10.1016/j.ceramint.2022.02.105

10. Garai M, Reka AA, Karmakar B, et al. Microstructure–mechanical properties of Ag0/Au0 doped K–Mg–Al–Si–O–F glass-ceramics. RSC Advances. 2021; 11(19): 11415-11424. doi: 10.1039/d0ra10519h

11. Das, S, Madheshiya A, Das S, et al. Mechanical, surface morphological and multi-objective optimization of tribological properties of V2O5 doped lead calcium titanate borosilicate glass ceramics. Ceramics International. 46(11): 19170-19180. doi: 10.1016/j.ceramint.2020.04.252

12. Karamanov A, Pisciella P, Pelino M. The effect of Cr2O3 as a nucleating agent in iron-rich glass-ceramics. Journal of European Ceramic Society. 1999; 19: 2641-2645. doi: 10.1016/S0955-2219(99)00047-3

13. Hubert M, Faber AJ, Akmaz F, et al. Stabilization of divalent chromium Cr(II) in soda-lime-silicate glasses. Journal of Non-Crystalline Solids. 2014; 403: 23-29. doi: 10.1016/j.jnoncrysol.2014.06.015

14. Singh K, Walia T. Review on silicate and borosilicate‐based glass sealants and their interaction with components of solid oxide fuel cell. International Journal of Energy Research. 2021; 45(151): 20559-20582. doi: https://doi.org/10.1002/er.7161

15. Rezvani M, Eftekhari-Yekta B, Solati-Hashjin M, et al. Effect of Cr2O3, Fe2O3 and TiO2 nucleants on the crystallization behaviour of SiO2-Al2O3-CaO-MgO(R2O) glass-ceramics. Ceramics International. 2005; 31(1): 75-80. doi: 10.1016/j.ceramint.2004.03.037

16. Oliver WC, Pharr GM. An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments. Journal of Materials Research. 1992; 7(6): 1564-1583. doi: 10.1557/jmr.1992.1564

17. Garai M, Murthy TSRCH, Karmakar B. Microstructural characterization and wear properties of silver and gold nanoparticle doped K-Mg-Al-Si-O-F glass-ceramics. Ceramics International. 2018; 44(18): 22308-22317. doi: 10.1016/j.ceramint.2018.08.356

18. Jahanshahi M, Mofidian R, Hosseini SS, et al. Investigation of mechanical properties of granular γ-alumina using experimental nano indentation and nano scratch tests. SN Applied Sciences. 2023; 5(6). doi: 10.1007/s42452-023-05388-7

19. Garai M, Singh CK, Rout SK. Crystallization and microstructure in K2O substituted SiO2-MgO-Al2O3-Li2O-AlPO4 glass-ceramics. Solid State Communications. 2022; 350: 114758. doi: 10.1016/j.ssc.2022.114758

20. Serbena FC, Mathias I, Foerster CE, et al. Crystallization toughening of a model glass-ceramic. Acta Materialia. 2015; 86: 216-228. doi: 10.1016/j.actamat.2014.12.007




DOI: https://doi.org/10.24294/can.v7i2.6046

Refbacks

  • There are currently no refbacks.


Copyright (c) 2024 Mrinmoy Garai, Arianit A. Reka, Shibayan Roy

License URL: https://creativecommons.org/licenses/by/4.0/

This site is licensed under a Creative Commons Attribution 4.0 International License.