Influence of green synthesized aluminum oxide nanoparticle concentration on wear and coefficient of friction of vegetable oil-based lubricants

Stephen Yebosoko Tsado, Tijani Jimoh Oladejo, Uzoma Gregory Okoro, Daniel Ipilakyaa Tertsegha, Ibrahim Ogu Sadiq, Joseph Abutu, Emmanuel Ogo Onche, Antwi Afari Acheampong, Alhassan Sullaiman, Ebenezer Adu Kyeremeh, Sunday Albert Lawal

Article ID: 4671
Vol 7, Issue 1, 2024

VIEWS - 1364 (Abstract) 572 (PDF)

Abstract


Green manufacturing is increasingly becoming popular, especially in lubricant manufacturing, as more environmentally friendly substitutes for mineral base oil and synthetic additives are being found among plant extracts and progress in methodologies for extraction and synthesis is being made. It has been observed that some of the important performance characteristics need enhancement, of which nanoparticle addition has been noted as one of the effective solutions. However, the concentration of the addictive that would optimised the performance characteristics of interest remains a contending area of research. The research was out to find how the concentration of green synthesized aluminum oxide nanoparticles in nano lubricants formed from selected vegetable oils influences friction and wear. A bottom-up green synthesis approach was adopted to synthesize aluminum oxide (Al2O3) from aluminum nitrate (Al(NO3)3) precursor in the presence of a plant-based reducing agent—Ipomoea pes-caprae. The synthesized Al2O3 nanoparticles were characterized using TEM and XRD and found to be mostly of spherical shape of sizes 44.73 nm. Al2O3 nanoparticles at different concentrations—0.1 wt%, 0.3 wt%, 0.5 wt%, 0.7 wt%, and 1.0 wt%—were used as additives to castor, jatropha, and palm kernel oils to formulate nano lubricants and tested alternately on a ball-on-aluminum (SAE 332) and low-carbon steel Disc Tribometer. All the vegetable-based oil nano lubricants showed a significant decrease in the coefficient of friction (CoF) and wear rate with Ball-on-(aluminum SAE 332) disc tribometer up to 0.5wt% of the nanoparticle: the best performances (eCOF = 92.29; eWR = 79.53) came from Al2O3-castor oil nano lubricant and Al2O3-palm kernel oil; afterwards, they started to increase. However, the performance indices displayed irregular behaviour for both COF and Wear Rate (WR) when tested on a ball-on-low-carbon steel Disc Tribometer.


Keywords


nanoparticles; green synthesized; wear; coefficient of friction; lubricants

Full Text:

PDF


References


1. Dai W, Kheireddin B, Gao H, et al. Roles of nanoparticles in oil lubrication. Tribology International. 2016; 102: 88-98. doi: 10.1016/j.triboint.2016.05.020

2. Ghaednia H, Hossain MS, Jackson RL. Tribological Performance of Silver Nanoparticle–Enhanced Polyethylene Glycol Lubricants. Tribology Transactions. 2016; 59(4): 585-592. doi: 10.1080/10402004.2015.1092623

3. Hwang Y, Lee JK, Lee JK, et al. Production and dispersion stability of nanoparticles in nanofluids. Powder Technology. 2008; 186(2): 145-153. doi: 10.1016/j.powtec.2007.11.020

4. Mohan D, Pittman CU, Bricka M, et al. Sorption of arsenic, cadmium, and lead by chars produced from fast pyrolysis of wood and bark during bio-oil production. Journal of Colloid and Interface Science. 2007; 310(1): 57-73. doi: 10.1016/j.jcis.2007.01.020

5. Lawal SA, Choudhury IA, Nukman Y. Application of vegetable oil-based metalworking fluids in machining ferrous metals—A review. International Journal of Machine Tools and Manufacture. 2012; 52(1): 1-12. doi: 10.1016/j.ijmachtools.2011.09.003

6. Salimon J, Abdullah BM, Salih N. Saponification of Jatropha curcas Seed Oil: Optimization by D-Optimal Design. International Journal of Chemical Engineering. 2012; 2012: 1-6. doi: 10.1155/2012/574780

7. Mahesar SA, Sherazi STH, Khaskheli AR, et al. Analytical approaches for the assessment of free fatty acids in oils and fats. Anal Methods. 2014; 6(14): 4956-4963. doi: 10.1039/c4ay00344f

8. Jeevanandam J, Barhoum A, Chan YS, et al. Review on nanoparticles and nanostructured materials: history, sources, toxicity and regulations. Beilstein Journal of Nanotechnology. 2018; 9: 1050-1074. doi: 10.3762/bjnano.9.98

9. Griffis C, Wilson T, Schneider J, Pierpont P. Unmanned Aircraft System Propulsion Systems Technology Survey. Available online: https://commons.erau.edu/cgi/viewcontent.cgi?article=1042&context=publication (accessed on 2 January 2024).

10. Trofymov I, Svyryd M, Matveyeva O, Sydorenko O. Influence of electromagnetic treatment of fuels and oils on the formation of wear resistance of friction pairs. In: Selected Aspects of Providing the Chemmotological Reliability of the Engineering. National Aviation University; 2019. pp. 141-153. doi: 10.18372/38236

11. Dai C, Zhang A, Liu M, et al. Hollow Alveolus-Like Nanovesicle Assembly with Metal-Encapsulated Hollow Zeolite Nanocrystals. ACS Nano. 2016; 10(8): 7401-7408. doi: 10.1021/acsnano.6b00888

12. Kart HH, Yildirim H, Ozdemir Kart S, et al. Physical properties of Cu nanoparticles: A molecular dynamics study. Materials Chemistry and Physics. 2014; 147(1-2): 204-212. doi: 10.1016/j.matchemphys.2014.04.030

13. Rastogi A, Zivcak M, Sytar O, et al. Impact of Metal and Metal Oxide Nanoparticles on Plant: A Critical Review. Frontiers in Chemistry. 2017; 5. doi: 10.3389/fchem.2017.00078

14. NadaroĞLu H, Güngör AA, Nce S. Synthesis of Nanoparticles by Green Synthesis Method Synthesis of Nanoparticles by Green Synthesis Method. International Journal of Innovative Research and Reviews. 2017; 1(1): 6-9.

15. Selma MA, Sarya DMA, Wafaa KK. Characterization of Laser Ablated Nanostructured Al2O3/p-Solar Cells. Iraqi Journal of Applied Physics. 2015; 11(1): 29-32.




DOI: https://doi.org/10.24294/can.v7i1.4671

Refbacks

  • There are currently no refbacks.


Copyright (c) 2024 Stephen Yebosoko Tsado, Tijani Jimoh Oladejo, Uzoma Gregory Okoro, Daniel Ipilakyaa Tertsegha, Ibrahim Ogu Sadiq, Joseph Abutu, Emmanuel Ogo Onche, Antwi Afari Acheampong, Alhassan Sullaiman, Ebenezer Adu Kyeremeh, Sunday Albert Lawal

License URL: https://creativecommons.org/licenses/by/4.0/

This site is licensed under a Creative Commons Attribution 4.0 International License.