Photocatalytic degradation of organic dyes using transition metal based mixed metal oxide nanocomposite under different illumination

R. Biju

doi:10.24294/can.v6i2.3573

Photocatalytic degradation of organic dyes using transition metal based mixed metal oxide nanocomposite under different illumination

R. Biju

Article ID: 3573
Vol 6, Issue 2, 2023

VIEWS - 2611 (Abstract)

Abstract

Nowadays, copper and zinc nanoparticles are widely employed in a variety of applications. With nanoscale particle sizes, copper oxide/zinc oxide composite is easily synthesized using a variety of techniques, including hydrothermal, microwave, precipitation, etc. In the current work, chemical precipitation is used to create a copper oxide/zinc oxide nanocomposite. XRD analysis was used to determine the nanocomposite’s structural characteristics. Through SEM analysis, the surface morphological properties are investigated. EDAX is used to study the chemical composition of produced materials, while UV/Visible spectroscopy is used to determine their optical properties. The assessment of the copper oxide/zinc oxide nanocomposite’s degrading property on dyes like methyl red and methyl orange under UV and visible light are the main objectives of the current work.

Keywords

nanocomposite; metal oxide; photocatalysis; methyl orange; methyl red

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References

Ali I, Irina B, Evgeny G, et al. High-speed and high-capacity removal of methyl orange and malachite green in water using newly developed mesoporous carbon: Kinetic and isotherm studies. ACS Omega 2019; 4(21): 19293–19306. doi: 10.1021/acsomega.9b02669 Alghamdi AA, Al-Odayni AB, Saeed WS, et al. Adsorption of azo dye methyl orange from aqueous solutions using alkali-activated polypyrrole-based graphene oxide. Molecules 2019; 24(20): 3685. doi: 10.3390/molecules24203685 Akansha K, Chakraborty D, Sachan SG. Decolorization and degradation of methyl orange by Bacillus stratosphericus SCA1007. Biocatalysis and Agricultural Biotechnology 2019; 18: 101044. doi: 10.1016/j.bcab.2019.101044 Mustafa G, Tahir H, Sultan M, Akhtar N. Synthesis and characterization of cupric oxide (CuO) nanoparticles and their application for the removal of dyes. African Journal of Biotechnology 2013; 12(47): 6650–6660. doi: 10.5897/AJB2013.13058 Kida T, Oka T, Nagano M, et al. Synthesis and application of stable copper oxide nanoparticle suspensions for nanoparticulate film fabrication. Journal of the American Ceramic Society 2007; 90(1): 107–110. doi: 10.1111/j.1551-2916.2006.01402.x Zhang W, Guo F, Wang F, et al. Synthesis of quinazolines via CuO nanoparticles catalyzed aerobic oxidative coupling of aromatic alcohols and amidines. Organic & Biomolecular Chemistry 2014; 12(30): 5752–5756. doi: 10.1039/c4ob00569d Prince Joshua J, Krishnan S, Vidhya Raj DJ, et al. Novel synthesis of tenorite (CuO) nanoparticles by wet chemical method. International Journal of ChemTech Research 2014; 6(3): 2002–2004. Mohan AC, Renjanadevi B. Preparation of zinc oxide nanoparticles and its characterization using scanning electron microscopy (SEM) and X-ray diffraction (XRD). Procedia Technology 2016; 24: 761–766. doi: 10.1016/j.protcy.2016.05.078 Biju R. Evaluation of the antibacterial properties of copper-based mixed metal oxide nanocomposite. Nano and Medical Materials 2023; 3(2): 261. doi: 10.59400/nmm.v3i2.261 Kumar H, Rani R. Structural and optical characterization of ZnO nanoparticles synthesized by microemulsion route. International Letters of Chemistry, Physics and Astronomy 2013; 19: 26–36. Wang H, Xie C, Zhang W, et al. Comparison of dye degradation efficiency using ZnO powders with various size scales. Journal of Hazardous Materials 2007; 141(3): 645–652. doi: 10.1016/j.jhazmat.2006.07.021 Zhang Y, Deng B, Zhang T, et al. Shape effects of Cu2O polyhedral microcrystals on photocatalytic activity. The Journal of Physical Chemistry C 2010; 114(11): 5073–5079. doi: 10.1021/jp9110037 Biju R, Ravikumar R, Thomas C, Indulal CR. Enhanced photocatalytic degradation of Metanil Yellow dye using polypyrrole-based copper oxide–zinc oxide nanocomposites under visible light. Journal of Nanoparticle Research 2022; 24(6): 117. doi: 10.1007/s11051-022-05495-3 Biju R, Ravikumar R, Thomas C, et al. Optimization and multifunctional applications of polypyrrole-modified copper oxide–zinc oxide nanocomposites. Arabian Journal for Science and Engineering 2023; 48(1): 919–937. doi: 10.1007/s13369-022-07199-1 Supin KK, Parvathy Namboothiri PM, Vasundhara M. Enhanced photocatalytic activity in ZnO nanoparticles developed using novel Lepidagathis ananthapuramensis leaf extract. RSC Advances 2023; 13(3): 1497–1515. doi: 10.1039/D2RA06967A Güell F, Galdámez-Martínez A, Martínez-Alanis PR, et al. ZnO-based nanomaterials approach for photocatalytic and sensing applications: Recent progress and trends. Materials Advances 2023; 4(17): 3685–3707. doi: 10.1039/D3MA00227F Bayat F, Sheibani S. Enhancement of photocatalytic activity of CuO-Cu2O heterostructures through the controlled content of Cu2O. Materials Research Bulletin 2022; 145: 111561. doi: 10.1016/j.materresbull.2021.111561 Alsulmi A, Mohammed NN, Soltan A, et al. Engineering S-scheme CuO/ZnO heterojunctions sonochemically for eradicating RhB dye from wastewater under solar radiation. RSC Advances 2023; 13(19): 13269–13281. doi: 10.1039/D3RA00924F Tariq SR, Niaz Z, Chotana GA, et al. Photocatalytic degradation of imidacloprid using Ag2O/CuO composites. RSC Advances 2023; 13(28): 19326–19334. doi: 10.1039/D3RA02109B Dien ND, Ha PTT, Vu XH, et al. Developing efficient CuO nanoplate/ZnO nanoparticle hybrid photocatalysts for methylene blue degradation under visible light. RSC Advances 2023; 13(35): 24505–24518. doi: 10.1039/D3RA03791F Anjum F, Shaban M, Ismail M, et al. Novel synthesis of CuO/GO nanocomposites and their photocatalytic potential in the degradation of hazardous industrial effluents. ACS Omega 2023; 8(20): 17667–17681. doi: 10.1021/acsomega.3c00129

DOI: https://doi.org/10.24294/can.v6i2.3573