Sulfonated mesoporous polystyrene-1D multiwall carbon nanotube nanocomposite as potential adsorbent for efficient removal of xylene isomers from aqueous solution

Mohan Raj Krishnan, Venugopal Rajendran

Article ID: 3516
Vol 6, Issue 2, 2023

VIEWS - 1387 (Abstract)

Abstract


Xylene isomers are notorious chemical hazards, and their efficient removal from water solutions is still challenging. The current study reports a polymer nanocomposite as a potential adsorbent for successfully removing dissolved xylene isomers from contaminated water. Polystyrene-1D multiwall carbon nanotube nanocomposite (PS-MWCNT) adsorbent was prepared using the one-step bulk polymerization method. Mesoporous PS-MWCNT was prepared using the nano-crystallization phase separation method. The sulfonation of the mesoporous PS-MWCNT nanocomposites was carried out by treating the samples with concentrated sulfuric acid at elevated temperatures. The sulfonated PS-MWCNT (HO3S-PS-MWCNT) was found to be a potential adsorbent for dissolved xylene isomers from water solution. In addition, the HO3S-PS-MWCNT can be efficiently recycled for up to 10 consecutive cycles with negligible decline in adsorption values. The exhibited equilibrium adsorption, rate of adsorption, and rapid regeneration of the HO3S-PS-MWCNT are clear indications for the possibility of practical utilization of these adsorbents in large-scale water treatment plants.


Keywords


polystyrene; carbon nanotube; nanocomposites; sulfonation; adsorption; xylene isomers

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References


Neff J, Lee K, DeBlois EM. Produced water: Overview of composition, fates, and effects. In: Lee K, Neff J (editors). Produced Water: Environmental Risks and Advances in Mitigation Technologies. Springer New York; 2011. pp. 3–54. doi: 10.1007/978-1-4614-0046-2_1 Al-Ghouti MA, Al-Kaabi MA, Ashfaq MY, Da’na DA. Produced water characteristics, treatment and reuse: A review. Journal of Water Process Engineering 2019; 28: 222–239. doi: 10.1016/j.jwpe.2019.02.001 Ray JP, Rainer Engelhardt F (editors). Produced Water: Technological/Environmental Issues and Solutions. Springer New York; 1992. doi: 10.1007/978-1-4615-2902-6 Wilson JM, VanBriesen JM. Oil and gas produced water management and surface drinking water sources in Pennsylvania. Environmental Practice 2012; 14(4): 288–300. doi: 10.1017/S1466046612000427 Clark CE, Veil JA. Produced Water Volumes and Management Practices in the United States. Argonne National Laboratory; 2009. doi: 10.2172/1007397 Hagström EL, Lyles C, Pattanayek M, et al. Produced water—Emerging challenges, risks, and opportunities. Environmental Claims Journal 2016; 28(2): 122–139. doi: 10.1080/10406026.2016.1176471 Krishnan MR, Aldawsari YF, Alsharaeh EH. Three-dimensionally cross-linked styrene-methyl methacrylate-divinyl benzene terpolymer networks for organic solvents and crude oil absorption. Journal of Applied Polymer Science 2021; 138(9): 49942. doi: 10.1002/app.49942 Krishnan MR, Aldawsari YF, Alsharaeh EH. 3D-poly(styrene-methyl methacrylate)/divinyl benzene-2D-nanosheet composite networks for organic solvents and crude oil spill cleanup. Polymer Bulletin 2021; 79: 3779–3802. doi: 10.1007/s00289-021-03565-5 Krishnan MR, Almohsin A, Alsharaeh EH. Mechanically robust and thermally enhanced sand-polyacrylamide-2D nanofiller composite hydrogels for water shutoff applications. Journal of Applied Polymer Science 2023. doi: 10.1002/app.54953 Tibbetts P, Buchanan I, Gawel L, Large R. A comprehensive determination of produced water composition. In: Ray JP, Engelhardt FR (editors). Produced Water: Technological/Environmental Issues and Solutions. Springer Boston; 1992. pp. 97–112. doi: 10.1007/978-1-4615-2902-6_9 Olsson O, Weichgrebe D, Rosenwinkel KH. Hydraulic fracturing wastewater in Germany: Composition, treatment, concerns. Environmental Earth Sciences 2013; 70: 3895–3906. doi: 10.1007/s12665-013-2535-4 Krishnan MR, Alsharaeh E. Potential removal of benzene-toluene-xylene toxic vapors by nanoporous poly(styrene-r-methylmethacrylate) copolymer composites. Environmental Nanotechnology, Monitoring & Management 2023; 20: 100860. doi: 10.1016/j.enmm.2023.100860 Krishnan MR, Almohsin A, Alsharaeh EH. Syntheses and fabrication of mesoporous styrene-co-methyl methacrylate-graphene composites for oil removal. Diamond and Related Materials 2022; 130: 109494. doi: 10.1016/j.diamond.2022.109494 Khoshakhlagh AH, Askari Majdabadi M, Yazdanirad S, Carlsen L. Health risk assessment of exposure to benzene, toluene, ethylbenzene, and xylene (BTEX) in a composite manufacturing plant: Monte-Carlo simulations. Human and Ecological Risk Assessment: An International Journal 2023; 29(3–4): 728–742. doi: 10.1080/10807039.2023.2167193 Khoshakhlagh AH, Yazdanirad S, Mousavi M, et al. Summer and winter variations of BTEX concentrations in an oil refinery complex and health risk assessment based on Monte-Carlo simulations. Scientific Reports 2023; 13: 10670. doi: 10.1038/s41598-023-37647-3 Suaidi NA, Alshawsh MA, Hoe S-Z, et al. Toxicological effects of technical xylene mixtures on the female reproductive system: A systematic review. Toxics 2022; 10(5): 235. doi: 10.3390/toxics10050235 Li H, Meng F, Li A. Ecological risk assessment for xylenes and propylbenzenes in aquatic environment using a species sensitivity distribution approach. Ecotoxicology and Environmental Safety 2023; 261: 115106. doi: 10.1016/j.ecoenv.2023.115106 Noh SR, Kim JA, Cheong HK, et al. Exposure to crude oil-related volatile organic compounds associated with lung function decline in a longitudinal panel of children. International Journal of Environmental Research and Public Health 2022; 19(23): 15599. doi: 10.3390/ijerph192315599 Yousef R, Qiblawey H, El-Naas MH. Adsorption as a process for produced water treatment: A review. Processes 2020; 8(12): 1657. doi: 10.3390/pr8121657 Ahmadun F-R, Pendashteh A, Abdullah LC, et al. Review of technologies for oil and gas produced water treatment. Journal of Hazardous Materials 2009; 170(2–3): 530–551. doi: 10.1016/j.jhazmat.2009.05.044 Wandera D, Ranil Wickramasinghe S, Husson SM. Modification and characterization of ultrafiltration membranes for treatment of produced water. Journal of Membrane Science 2011; 373(1–2): 178–188. doi: 10.1016/j.memsci.2011.03.010 Deriszadeh A, Husein MM, Harding TG. Produced water treatment by micellar-enhanced ultrafiltration. Environmental Science & Technology 2010; 44(5): 1767–1772. doi: 10.1021/es902862j Mondal S, Ranil Wickramasinghe S. Produced water treatment by nanofiltration and reverse osmosis membranes. Journal of Membrane Science 2008; 322(1): 162–170. doi: 10.1016/j.memsci.2008.05.039 Shams Ashaghi K, Ebrahimi M, Czermak P. Ceramic ultra- and nanofiltration membranes for oilfield produced water treatment: A mini review. Open Environmental Sciences 2007; 1: 1–8. doi: 10.2174/1876325100701010001 Sadrzadeh M, Pernitsky D, McGregor M. Nanofiltration for the treatment of oil sands-produced water. In: Farrukh MA (editor). Nanofiltration. IntechOpen; 2018. doi: 10.5772/intechopen.74086 Chang H, Liu B, Yang B, et al. An integrated coagulation-ultrafiltration-nanofiltration process for internal reuse of shale gas flowback and produced water. Separation and Purification Technology 2019; 211: 310–321. doi: 10.1016/j.seppur.2018.09.081 Peng Y, Wei X, Wang Y, et al. Metal–organic framework composite photothermal membrane for removal of high-concentration volatile organic compounds from water via molecular sieving. ACS Nano 2022; 16: 8329–8337. doi: 10.1021/acsnano.2c02520 Costa TC, Hendges LT, Temochko B, et al. Evaluation of the technical and environmental feasibility of adsorption process to remove water soluble organics from produced water: A review. Journal of Petroleum Science and Engineering 2022; 208: 109360. doi: 10.1016/j.petrol.2021.109360 Khader EH, Mohammed TJ, Mirghaffari N, et al. Removal of organic pollutants from produced water by batch adsorption treatment. Clean Technologies and Environmental Policy 2022; 24: 713–720. doi: 10.1007/s10098-021-02159-z Eftekhardadkhah M, Aanesen SV, Rabe K, Øye G. Oil removal from produced water during laboratory-and pilot-scale gas flotation: The influence of interfacial adsorption and induction times. Energy & Fuels 2015; 29(11): 7734–7740. doi: 10.1021/acs.energyfuels.5b02110 Jiménez S, Micó MM, Arnaldos M, et al. State of the art of produced water treatment. Chemosphere 2018; 192: 186–208. doi: 10.1016/j.chemosphere.2017.10.139 Rout DR, Jena HM, Baigenzhenov O, Hosseini-Bandegharaei A. Graphene-based materials for effective adsorption of organic and inorganic pollutants: A critical and comprehensive review. Science of The Total Environment 2023; 863: 160871. doi: 10.1016/j.scitotenv.2022.160871 Oladoye PO. Natural, low-cost adsorbents for toxic Pb(II) ion sequestration from (waste)water: A state-of-the-art review. Chemosphere 2022; 287: 132130. doi: 10.1016/j.chemosphere.2021.132130 Varsha M, Senthil Kumar P, Senthil Rathi B. A review on recent trends in the removal of emerging contaminants from aquatic environment using low-cost adsorbents. Chemosphere 2022; 287: 132270. doi: 10.1016/j.chemosphere.2021.132270 Eniola JO, Sizirici B, Fseha Y, et al. Application of conventional and emerging low-cost adsorbents as sustainable materials for removal of contaminants from water. Environmental Science and Pollution Research 2023; 30: 88245–88271. doi: 10.1007/s11356-023-28399-8 Dehghani MH, Afsari Sardari S, Afsharnia M, et al. Removal of toxic lead from aqueous solution using a low-cost adsorbent. Scientific Reports 2023; 13: 3278. doi: 10.1038/s41598-023-29674-x Bilal M, Ihsanullah I, Younas M, Ul Hassan Shah M. Recent advances in applications of low-cost adsorbents for the removal of heavy metals from water: A critical review. Separation and Purification Technology 2021; 278: 119510. doi: 10.1016/j.seppur.2021.119510 Yan M, Rong Y, Wu F, et al. Micro-mesoporous graphitized carbon fiber as hydrophobic adsorbent that removes volatile organic compounds from air. Chemical Engineering Journal 2023; 452: 139184. doi: 10.1016/j.cej.2022.139184 Samitsu S, Zhang R, Peng X, et al. Flash freezing route to mesoporous polymer nanofibre networks. Nature Communications 2013; 4: 2653. doi: 10.1038/ncomms3653. Chien Y-C, Huang L-Y, Yang K-C, et al. Fabrication of metallic nanonetworks via templated electroless plating as hydrogenation catalyst. Emergent Materials 2021; 4: 493–501. doi: 10.1007/s42247-020-00108-y Krishnan MR, Samitsu S, Fujii Y, Ichinose I. Hydrophilic polymer nanofibre networks for rapid removal of aromatic compounds from water. Chemical Communications 2014; 66: 9393–9396. doi: 10.1039/C4CC01786B Liu X, Li Y, Chen Z, et al. Advanced porous nanomaterials as superior adsorbents for environmental pollutants removal from aqueous solutions. Critical Reviews in Environmental Science and Technology 2023; 53(13): 1289–1309. doi: 10.1080/10643389.2023.2168473 Krishnan MR, Omar H, Almohsin A, Alsharaeh EH. An overview on nanosilica–polymer composites as high-performance functional materials in oil fields. Polymer Bulletin 2023. doi: 10.1007/s00289-023-04934-y Krishnan MR, Aldawsari Y, Michael FM, et al. Mechanically reinforced polystyrene-polymethyl methacrylate copolymer-graphene and Epoxy-Graphene composites dual-coated sand proppants for hydraulic fracture operations. Journal of Petroleum Science and Engineering 2021; 196: 107744. doi: 10.1016/j.petrol.2020.107744 Krishnan MR, Aldawsari Y, Michael FM, et al. 3D-Polystyrene-polymethyl methacrylate/divinyl benzene networks-Epoxy-Graphene nanocomposites dual-coated sand as high strength proppants for hydraulic fracture operations. Journal of Natural Gas Science and Engineering 2021; 88: 103790. doi: 10.1016/j.jngse.2020.103790 Michael FM, Krishnan MR, Li W, Alsharaeh EH. A review on polymer-nanofiller composites in developing coated sand proppants for hydraulic fracturing. Journal of Natural Gas Science and Engineering 2020; 83: 103553. doi: 10.1016/j.jngse.2020.103553 Krishnan MR, Michael FM, Almohsin A, Alsharaeh EH. Polyacrylamide hydrogels coated super-hydrophilic sand for enhanced water storage and extended release. SSRN Electronic Journal 2022. doi: 10.2139/ssrn.4232876 Krishnan MR, Li W, Alsharaeh EH. Ultra-lightweight nanosand/polymer nanocomposite materials for hydraulic fracturing operations. SSRN e-Journal 2022. doi: 10.2139/ssrn.4233321 Almohsin AM, Alsharaeh E, Krishnan MR, Alghazali M. Coated Nanosand as Relative Permeability Modifier. U.S. Patent 20,230,060,690A1, 2 March 2023. Li W, Alsharaeh E, Krishnan MR. Coated Proppants and Methods of Making and Use Thereof. U.S. Patent 20,230,313,027A1, 5 October 2023. Li W, Alsharaeh E, Krishnan MR. Proppant Coatings and Methods of Making. U.S. Patent 20,210,395,603A1, 23 December 2021. Li W, Alsharaeh E, Krishnan MR. Methods for Making Proppant Coatings. U.S. Patent 11,459,503, 4 October 2022. Krishnan MR, Omar H, Aldawsari Y, et al. Insight into thermo-mechanical enhancement of polymer nanocomposites coated microsand proppants for hydraulic fracturing. Heliyon 2022; 8(12): e12282. doi: 10.1016/j.heliyon.2022.e12282 Krishnan MR, Alsharaeh EH. Polymer gel amended sandy soil with enhanced water storage and extended release capabilities for sustainable desert agriculture. Journal of Polymer Science and Engineering 2023; 6(1): 2892. doi: 10.24294/jpse.v6i1.2892 Alsharaeh EH, Krishnan MR. Method of Making Mutlilayer Soil with Property for Extended Release Water for Desert Agriculture. U.S. Patent 10,772,265, 15 September 2020. Krishnan MR, Li W, Alsharaeh EH. Cross-linked polymer nanocomposite networks coated nano sand light-weight proppants for hydraulic fracturing applications. Characterization and Application of Nanomaterials 2023; 6(2): 3314. doi: 10.24294/can.v6i2.3314 Krishnan MR, Almohsin A, Alsharaeh EH. Thermo-mechanically reinforced mesoporous styrene-Co-methyl methacrylate-graphene composites for produced water treatment. SSRN 2022. Cheng C-F, Chen Y-M, Zou F, et al. Li-ion capacitor integrated with nano-network-structured Ni/NiO/C anode and nitrogen-doped carbonized metal–organic framework cathode with high power and long cyclability. ACS Applied Materials Interfaces 2019; 11(34): 30694–30702. doi: 10.1021/acsami.9b06354 Lo T-Y, Krishnan MR, Lu K-Y, Ho R-M. Silicon-containing block copolymers for lithographic applications. Progress in Polymer Science 2018; 77: 19–68. doi: 10.1016/j.progpolymsci.2017.10.002 Krishnan MR, Lu K, Chiu W, et al. Directed self‐assembly of star‐block copolymers by topographic nanopatterns through nucleation and growth mechanism. Small 2018; 14: 1704005. Keishnan MR, Michael FM, Almohsin AM, Alsharaeh EH. Thermal and rheological investigations on N,N’-methylenebis acrylamide cross-linked polyacrylamide nanocomposite hydrogels for water shutoff applications. In: Offshore Technology Conference Asia; 2–6 November 2020; Kuala Lumpur, Malaysia. doi: 10.4043/30123-MS Krishnan MR, Rajendran V, Alsharaeh E. Anti-reflective and high-transmittance optical films based on nanoporous silicon dioxide fabricated from templated synthesis. Journal of Non-Crystalline Solids 2023; 606: 122198. doi: 10.1016/j.jnoncrysol.2023.122198 Krishnan M, Chen H-Y, Ho R-M. Switchable structural colors from mesoporous polystyrene films. In: 252nd ACS National Meeting; 18–26 August 2016; Philadelphia, Pennsylvania, USA. Ho R-M, Krishnan MR, Siddique SK, Chien Y-C. Method for Fabricating Nanoporous Polymer Thin Film and Corresponding Method for Fabricating Nanoporous Thin Film. U.S. Patent, 20,190,255,745, 17 August 2018. Aldosari MA, Alsaud KBB, Othman A, et al. Microwave irradiation synthesis and characterization of reduced-(graphene oxide-(polystyrene-polymethyl methacrylate))/silver nanoparticle nanocomposites and their anti-microbial activity. Polymers 2020; 12(5): 1155. doi: 10.3390/polym12051155 Sajid M, Asif M, Baig N, et al. Carbon nanotubes-based adsorbents: Properties, functionalization, interaction mechanisms, and applications in water purification. Journal of Water Process Engineering 2022; 47: 102815. doi: 10.1016/j.jwpe.2022.102815 Manimegalai S, Vickram S, Deena SR, et al. Carbon-based nanomaterial intervention and efficient removal of various contaminants from effluents—A review. Chemosphere 2023; 312: 137319. doi: 10.1016/j.chemosphere.2022.137319 Mishra S, Sundaram B. Efficacy and challenges of carbon nanotube in wastewater and water treatment. Environmental Nanotechnology, Monitoring & Management 2023; 19: 100764. doi: 10.1016/j.enmm.2022.100764 Almohsin A, Alsharaeh E, Krishnan MR. Polymer-Sand Nanocomposite Lost Circulation Material. U.S. Patent 20,230,142,223A1, 11 May 2023. Krishnan MR, Alsharaeh EH. A review on polymer nanocomposites based high-performance functional materials. SSRN 2022. Bongu CS, Krishnan MR, Soliman A, et al. Flexible and freestanding MoS2/graphene composite for high-performance supercapacitors. ACS Omega 2023; 8(40): 36789–36800. doi: 10.1021/acsomega.3c03370 Almohsin A, Alsharaeh E, Michael FM, Krishnan MR. Polymer-Nanofiller Hydrogels. U.S. Patent 20,220,290,033A1, 15 September 2022. Krishnan M, Michal F, Alsoughayer S, et al. Thermodynamic and kinetic investigation of water absorption by PAM composite hydrogel. In: SPE Kuwait Oil & Gas Show and Conference; 13–16 October 2019; Mishref, Kuwait. doi: 10.2118/198033-MS Almohsin A, Michal F, Alsharaeh E, et al. Self-healing PAM composite hydrogel for water shutoff at high temperatures: Thermal and rheological investigations. In: SPE Gas & Oil Technology Showcase and Conference; 21–23 October 2019; Dubai, UAE. doi: 10.2118/198664-MS Michael FM, Krishnan MR, Fathima A, et al. Zirconia/graphene nanocomposites effect on the enhancement of thermo-mechanical stability of polymer hydrogels. Materials Today Communications 2019; 21: 100701. doi: 10.1016/j.mtcomm.2019.100701 Almohsin A, Krishnan MR, Alsharaeh E, Harbi B. Preparation and properties investigation on sand-polyacrylamide composites with engineered interfaces for water shutoff applications. In: Middle East Oil, Gas and Geosciences Show; 19–21 February 2023; Manama, Bahrain. doi: 10.2118/213481-MS Krishnan MR, Chien YC, Cheng CF, Ho RM. Fabrication of mesoporous polystyrene films with controlled porosity and pore size by solvent annealing for templated syntheses. Langmuir 2017; 33(34): 8428–8435. doi: 10.1021/acs.langmuir.7b02195 Sun L, Yuan D, Liu R, et al. Coadsorption of gaseous xylene, ethyl acetate and water onto porous biomass carbon foam pellets derived from liquefied Vallisneria natans waste. Journal of Chemical Technology & Biotechnology 2020; 95(5): 1348–1360. doi: 10.1002/jctb.6319 Yan X, Xie Y, Zhao S, et al. Preparation of modified superhydrophobic sponge and its application in xylene leakage recovery. Desalination and Water Treatment 2020; 201: 187–194. Ece MŞ, Kutluay S. Comparative and competitive adsorption of gaseous toluene, ethylbenzene, and xylene onto natural cellulose-modified Fe3O4 nanoparticles. Journal of Environmental Chemical Engineering 2022; 10: 107389. doi: 10.1016/j.jece.2022.107389 Chin C-JM, Shih L-C, Tsai H-J, Liu T-K. Adsorption of o-xylene and p-xylene from water by SWCNTs. Carbon 2007; 45: 1254–1260. doi: 10.1016/j.carbon.2007.01.015



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