Nanodemulsifiers with the properties of crystalline liquids, intramolecular interblock activity and eternal intramolecular nanomotors

Dashdiyev Rahim Abas; Dashdiyeva Turana Kamil

doi:10.24294/can.v6i2.3008

Nanodemulsifiers with the properties of crystalline liquids, intramolecular interblock activity and eternal intramolecular nanomotors

Dashdiyev Rahim Abas, Dashdiyeva Turana Kamil

Article ID: 3008
Vol 6, Issue 2, 2023

VIEWS - 2416 (Abstract) 861 (PDF)

Abstract

The provided material presents a priority article on the scientific discovery titled “The phenomenon of simultaneous destruction of water-oil and oil-water emulsions”. The authors propose the corresponding formula: the previously unknown phenomenon of simultaneous destruction of water-oil and oil-water emulsions occurs when polynanostructured surfactant demulsifiers with characteristics akin to crystalline liquids, intramolecular interblock activity, and enduring intramolecular nanomotors (such as block copolymers of ethylene and propylene oxides, which act as sources of oligomer homologues of oxyethylene ethers) are added to crude oil during primary oil processing. This phenomenon is attributed to the redistribution of oligomer homologues, with the most hydrophobic oxyethylene ethers being dispersed in water-oil emulsions and the most hydrophilic ones in oil-water emulsions, resulting in robust nanodispersed phases with crystalline liquid properties.

Keywords

the phenomenon of simultaneous destruction of water-oil and oil-water emulsions; polynanostructured surfactant demulsifiers; crystalline liquids; intramolecular interblock activity; eternal intramolecular nanomotors

Full Text:

PDF

References

1. Mirzajanzadeh AK. Nanohydrodynamic effects based on the use of micronucleation technology (Russian). Mirzajanzade AK, Bakhtizin RN, Mustafaev AA et al. Oilfield Business, Moscow: 2005. (3): 311–315.

2. Ismayilov FS. On the results of industrial testing of the nanodemulsifier ND-1/4 for the demulsification of hard-to-break water-oil emulsion of the Zhetybai field (Russian). Ismayilov FS, Dashdiev RA, Dashdieva NJ et al. Azerbaijan Oil Industry, Baku: 2015. 1: 39–45.

3. Semihina LP, Shtykov SV, Karelin EA. Research of reagents suitability for eor, by their oil slicks detergency. Oil and Gas Business 2015; (5): 236–256. doi: 10.17122/ogbus-2015-5-236-256

4. Kelbaliev GI, Rasulov SR, Mustafaeva GR. Modeling of droplet coalescence phenomena in the processes of separation of oil emulsions. Chemistry and Technology of Fuels and Oils 2018; 54: 158–165. doi: 10.1007/s10553-018-0910-2

5. Li J, Xu C, Yin G, Zhao F. Dendritic Reverse Demulsifier and Preparation Method Thereof. Patent 102233249, 9 September 2011.

6. Dashdiyeva TK. Nanotechnology in the oil and water preparation using nanodemulsifiers. International Journal of Innovative Research in Science, Engineering and Technology 2019; 9(8): 9477–9487. doi: 10.15680/IJIRSET.2019.0809047

7. Pashayev AM, Dashdiyev RA, Yang SJ, et al. Polynanobarrier properties of crude oil. International Journal of Advanced Trends in Engineering and Technology 2021; 6(1): 1–31.

8. First electric nanomotor made from DNA material. Available online: https://www.ds.mpg.de/3949715/220721_DNA-nanomotors (accessed on 28 September 2023).

9. Nanomotor. Available online: https://en.wikipedia.org/wiki/Nanomotor (accessed on 28 September 2023).

10. Nanomotor: How a motor created by bacteria works. Available online: https://vk.com/@science_newworld-nanodvigatel-kak-rabotaet-motor-sozdannyi-bakteriyami (accessed on 28 September 2023).

11. A nanomotor has been created that can rotate at a speed of 150 thousand revolutions per minute (Russian). Avaialble online: https://luckyea77.livejournal.com/280381.html (accessed on 28 September 2023).

12. A unique nanomotor was invented at Cambridge University (Russian). Available online: https://fainaidea.com/izobretenija/prototipy/v-kembridzhskom-universitete-izobrel-102144.html (accessed on 28 September 2023).

13. Zhong’s Generator—A perpetual nanomotor was invented in China (Russian) Available online: https://www.infoabad.com/478-generator-chzhuna-v-kitae-izobreten-vechnyi-nanodvigatel.html (accessed on 28 September 2023).

14. Dashdiev RA, Shi P, Dashdieva NJ, et al. Scientific hypothesis on the desuspensing properties of surfactants in oil suspensions when polynanostructural associative surfactants are added to it (Russian). Diploma No. 02Г-2021, Moscow, Hannover, publ. 3 April 2021.

15. Dashdiev RA, Shi P, Dashdieva NJ. et al. Properties of multiblock surfactants similar in structure to block copolymers of ethylene and propylene oxides (Russian). Diploma for scientific discovery No. 03-2021, Moscow, Hannover, publ. 29 Apr 2021.

16. Dashdiev RA, Shi P, Dashdieva NJ, et al. The property of inhibiting the formation of ultra-resistant, hard to destroy water-oil emulsions, suspensions (Russian). Diploma for scientific discovery No. 04-2021, Moscow, Hannover, publ. 31 May 2021.

17. Pashayev AM, Dashdiyev RA, Yang SJ, et al. Polynanobarrier properties of crude oil (Russian). Diploma for scientific discovery No. 02-2022, Moscow, Hannover, publ. 17 November 2022.

18. Pashayev AM, Dashdiyev RA, Yang SJ, et al. Theoretically substantiated and experimentally confirmed the previously unknown property of equivalently crosslinked polymers to create long-term self-protection. Diploma for scientific discovery No. 01-2023, Moscow, Hannover, publ. 5 May 2023.

19. Dashdiyev RA, Yang SJ, Lyu B, et al. The phenomenon of simultaneous destruction of water-oil and oil-water emulsions. Diploma for scientific discovery No. 01-2023, Moscow, Hannover, publ. 2023.

20. GOST 31378–2009. Oil. General Technical Conditions (Russian). Standartinform Publisher; 2019. p. 13.

21. OST 39–225–88 (OST 39–133–81). Water for flooding oil reservoirs. Quality requirements. M.: 2003. p. 10.

22. GOST 2477–2014. Oil and Petroleum Products. Method for Determining Water Content (Russian). Standartinform Publisher; 2018. p. 16.

23. GOST 21534–76. Oil Methods for Determining the Content of Chloride Salts (Russian). IPK Publishing House of Standards; 2003. p. 33.

24. GOST 6370–2018. Oil, petroleum products and impurities. Method for determining mechanical impurities (Russian). M.: Arial Headset, 2018. 6.

25. Nugmanov AK, Dashdiev RA, Dashdieva TK, et al. Demulsifier for the Destruction of Oil-water and Oil-water Emulsions. Patent 30960, 15 March 2016.

26. Dashdiyeva TK. Development and application of nanodemulsifiers for the treatment of formation—Waters from oil in conditions of primary preparation of oil (Azerbaijani). Azerbaijan Journal of Chemical News 2020; 2(1): 68–76.

27. Requirements for demulsifiers (Russian). Available online: https://studopedia.org/13-60853.html (accessed on 28 September 2023).

28. All-Russian conference with international participation “Physico-chemical problems of adsorption, structure and surface chemistry of nanoporous materials” dedicated to the 120th anniversary of the birth of M.M. Dubinin (Russian). Collection of abstracts of reports, M.: Institute of Physics and Chemistry of the Russian Academy of Sciences, 18–22 October 2021. p. 322.

29. Gasanov AA, Dashdiyeva TK. On the results of calculation of adsorption for liquid-crystalline nanodemulsifiers on the basis of the oxialykylene block copolymers. Baku, Azerbaijan Chemistry Journal 2018; 3: 103–111.

30. Gumbatov GG, Dashdiev RA. Application of surfactants to eliminate emergency oil spills on the water surface (Russian). Baku: Elm, 1998. p. 210.

31. Gasanov AA, Dashdiyeva TK. Isolation and identification of individual oxyethyl esters of n-aliphatic acids using critical nanoemulsions. Russian Journal of General Chemistry 2017; 87(8): 1771–1774.

32. Schoenfeld N, Kovalenko LV. Surfactants based on ethylene oxide. Moscow: Chemistry, 1982. p. 749.

33. Abramzon AA, Gaeva GM. Surface active substances (Russian). Leningrad: Chemistry, 1979. p. 376.

34. Gasanov AA, Daşdiyeva TK. Results of experimental-industrial tests of nanodemulsifier “IKHLAS-1” on the objects JSC “Ozenmunaigaz” RK. Azerbaijan Journal Chemical News 2022; 4(2): 23–31. doi: 10.32010/ajcn04042022-23

35. Gasanov AA, Dashdiyeva TK. The results of studies crude oil demulsification in the conditions of primary preparation of oil of some difficult fields of the Republic of Kazakhstan. Azerbaijan Journal Chemical News 2023; 2(5): 33–40.

DOI: https://doi.org/10.24294/can.v6i2.3008