Using aqueous extract of Eucalyptus grandis to synthesize iron oxide nanoparticles

Santiago Eduardo Pabón-Guerrero; Ricardo Benítez-Benítez; Rodrigo Andrés Sarria-Villa; José Antonio Gallo-Corredor

doi:10.24294/can.v5i2.1691

Using aqueous extract of Eucalyptus grandis to synthesize iron oxide nanoparticles

Santiago Eduardo Pabón-Guerrero, Ricardo Benítez-Benítez, Rodrigo Andrés Sarria-Villa, José Antonio Gallo-Corredor

Article ID: 1691
Vol 5, Issue 2, 2022

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Abstract

This work presents the evaluation of iron oxide nanoparticles obtained from the aqueous extract of Eucalyptus grandis. Twenty-three experiments were carried out where the synthesis of nanoparticles was performed by using the aqueous extract together with salts of iron (II) chloride tetrahydrate and iron (III) chloride hexahydrate. A characterization was carried out by IR, TEM and BET, where bands were presented at 3,440.77, 1,559.26 and 445.31 cm⁻¹, indicating the presence of iron oxide nanoparticles. A relatively high monodispersity was evidenced with particles around 9 nm. By means of BET analysis it was found to present a surface area of 131.897 m²/g. Obtaining nanoparticles by this green method presents yield values of 98%, with application in nanotechnology, biomedicine, environmental treatment, among others, making them highly versatile and their production cost is relatively low.

Keywords

Green Synthesis; Magnetite Nanoparticles; Plant Extract

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References

1. del Rio Clar M. Application of magnetic iron nanoparticles to the removal of mercury from water (in Spanish) [BSc thesis]. Palma de Mallorca Departamento de Química: Universidad de les Illes Balears; 2013.

2. Mazrouaa AM, Mohamed MG, Fekry M. Physical and magnetic properties of iron oxide nanoparticles with a different molar ratio of ferrous and ferric. Egyptian Journal of Petroleum 2019; 28(2): 165–171. doi: 10.1016/j.ejpe.2019.02.002.

3. Garcia IN. Green synthesis of nanoparticles to remove dyes in aqueous media [thesis]. A Coruña: Universidade da Coruña; 2015.

4. Stan M, Lung I, Soran ML, et al. Removal of antibiotics from aqueous solutions by green synthesized magnetite nanoparticles with selected agro-waste extracts. Process Safety and Environmental Protection 2017; 107: 357–372. doi: 10.1016/j.psep.2017.03.003.

5. Awwad AM, Salem NM. A green and facile approach for synthesis of magnetite nanoparticles. Nanoscience and Nanotechnology 2012; 2(6): 208–213. doi: 10.5923/j.nn.20120206.09.

6. Ahmed MA, Ali SM, El-Dek SI, et al. Magnetite–hematite nanoparticles prepared by green methods for heavy metal ions removal from water. Materials Science and Engineering: B 2013; 178(10): 744–751. doi: 10.1016/j.mseb.2013.03.011.

7. Martínez-Montemayor S. Pure, composite and hybrid magnetic materials (in Spanish). Saltillo: Centro de Investigación en Química Aplicada; 2006.

8. Lopez-Brito K. Synthesis of nanostructured hybridized compounds and evaluation of their supramolecular behavior and biological activity [PhD thesis]. Palma de Mallorca: Universidad de les Illes Balears; 2013.

9. Noval VE, Ochoa Puentes C, Carriazo JG. Magnetite (Fe3O4): An inorganic structure with multiple applications in heterogeneous catalysis (in Spanish). Revista Colombiana de Química 2017; 46(1): 42–59. doi: 10.15446/rev.colomb.quim.v45n1.62831.

10. Zanella R. Methodologies for the synthesis of nanoparticles: Controlling shape and size (in Spanish). Mundo nano. Revista Interdisciplinaria en Nanociencias y Nanotecnología 2012; 5(1): 69–81.

11. Laurent S, Forge D, Port M, et al. Magnetic iron oxide nanoparticles: synthesis, stabilization, vectorization, physicochemical characterizations, and biological applications. Chemical Reviews 2008; 108(6): 2064–2110.

12. Hasany SF, Ahmed I, Rajan J, et al. Systematic review of the preparation techniques of iron oxide magnetic nanoparticles. Nanoscience and Nanotechnology 2012; 2(6): 148–158. doi: 10.5923/j.nn.20120206.01.

13. Buendía Aceves S. Synthesis of iron nanoparticles with magnetic properties obtained via organometallic precursors (in Spanish) [MSc thesis]. Mexico City: Sección de Estudios de Posgrado e Investigación, Instituto Politécnico Nacional; 2009.

14. Robles Ardila DP, Rodríguez Pardo N, Pataquiva-Mateus A. Synthesis of magnetite nanoparticles from papaya peel extract for the degradation of azo dyes in aqueous solutions (in Spanish). Ingeniare. Revista Chilena de Ingeniería 2019; 27(3): 431–442. doi: 10.4067/S0718-33052019000300431.

15. Mohmood I, Lopes CB, Lopes I, et al. Remediation of mercury contaminated saltwater with functionalized silica coated magnetite nanoparticles. Science of the Total Environment 2016; 557–558: 712–721. doi: 10.1016/j.scitotenv.2016.03.075.

16. Hasnain MS, Javed MN, Alam MS, et al. Purple heart plant leaves extract-mediated silver nanoparticle synthesis: Optimization by Box-Behnken design. Materials Science and Engineering: C 2019; 99: 1105–1114. doi: 10.1016/j.msec.2019.02.061.

17. Alvear D, Galeas S, Guerrero VH, et al. Synthesis and characterization of magnetite nanoparticles (in Spanish). Revista Politécnica 2017; 39(2): 61–66. doi: 10.33333/rp.v39i2.545.

DOI: https://doi.org/10.24294/can.v5i2.1691