Synthesis and properties of ordered mesoporous TiO2 and their composites

Wei Zhou, Honggang Fu, Kai Pan

Article ID: 1359
Vol 4, Issue 2, 2021, Article identifier:100-109

VIEWS - 119 (Abstract) 57 (PDF)

Abstract


Ordered mesoporous TiO2 and their composites have many potential applications in the fields of photocatalysis‚ solar-cells, and so on, due to their special microstructures. The synthesized methods of ordered mesoporous TiO2 were classified systematically in this paper. The synthesized approaches‚development history, classification and application of mesoporous TiO2 and their composites are reviewed. Some important progress and research results are also summarized. Based on the present existing problems, the development trend is discussed.

Keywords


Mesoporous TiO2; Composite; Photocatalysis

Full Text:

PDF

Included Database


References


Kresge CT, Leonowicz ME, Roth WJ, et al.Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism. Nature 1992; 359(6397): 710–712.

Zhou W, Fu H, Pan K, et al. Preparation of mesoporous TiO2/CdS thin film photoelectrode through electrodeposition. Chemical Journal of Chinese Universities 2010; 31(1): 112–116.

Zhou W, Fu H, Pan K, et al. Preparation of mesoporous TiO2/single wall carbon nanotubes thin film through electrophoretic deposition. Chemical Journal of Chinese Universities 2009; 30(10): 2036–2039.

Zhao J, Wan P, Xiang J, et al. Synthesis of highly ordered macro-mesoporous anatase TiO2 film with high photocatalytic activity. Microporous and Mesoporous Materials 2011; 138(1-3): 200–206.

Kim YJ, Lee YH, Lee MH, et al. Formation of efficient dye-sensitized solar cells by introducing an interfacial layer of long-range ordered mesoporous TiO2 thin film. Langmuir 2008; 24(22): 13225–13230.

Lee J, Orilall1 MC, Warren SC, et al. Direct access to thermally stable and highly crystalline mesoporous transition-metal oxides with uniform pores. Nature Materials 2008; 7(3): 222–228.

Patra AK, Das SK, Bhaumik A. Self-assembled mesoporous TiO2 spherical nanoparticles by a new templating pathway and its enhanced photoconductivity in the presence of an organic dye. Journal of Materials Chemistry 2011; 21(11): 3925–3930.

Kao L, Hsu T, Cheng K. Novel synthesis of high-surface-area ordered mesoporous TiO2 with anatase framework for photocatalytic application. Journal of Colloid and Interface Science 2010; 341(2): 359–365.

Gnatyuk Y, Smirnova AN, Kordubanb O, et al. Effect of zirconium incorporation on the stabilization of TiO2 mesoporous structure. Surface and Interface Analysis 2010; 42(6-7): 1276–1280.

Chen X, Wang X, Fu X. Hierarchical macro/mesoporous TiO2/SiO2 and TiO2/ZrO2 nanocomposites for environmental photocatalysis. Energy Environmental Science 2009; 2: 872–877.

Piris J, Ferguson AJ, Blackburn JL, et al. Efficient photoinduced charge injection from chemical bath deposited CdS into mesoporous TiO2 probed with time-resolved microwave conductivity. The Journal of Physical Chemistry C 2008; 112(20): 7742–7749.

Chen H, Li W, Liu H, et al. Performance enhancement of CdS-sensitized TiO2 mesoporous electrode with two different sizes of CdS nanoparticles. Microporous and Mesoporous Materials 2011; 138(1-3): 235–238.

Ciriminna R, Sciortino M, Alonzo G, et al. From molecules to systems: Sol-gel microencapsulation in silica-based materials. Chemical Reviews 2011; 111(2): 765–789.

Song L, Feng D, Fredin JN, et al. Challenges in fabrication of mesoporous carbon films with ordered cylindrical pores via phenolic oligomer self-assembly with triblock copolymers. ACS Nano 2010; 4(1): 189–198.

Gierszal PK, Jaroniec M. Carbons with extremely large volume of uniform mesopores synthesized by carbonization of phenolic resin film formed on colloidal silica template. Journal of the American Chemical Society 2006; 128(31): 10026–10027.

Forster S, Antonietti M. Amphiphilic block copolymers in structure-controlled nanomaterial hybrids. Advanced Materials 1998; 10(3): 195–217.

Wu C, Ohsuna T, Kuwabara M, et al. Formation of highly ordered mesoporous titania films consisting of crystalline nanopillars with inverse mesospace by structural transformation. Journal of the American Chemical Society 2006; 128(14): 4544–4545.

Crepaldi EL, Soler-Illia GJAA, Grosso D, et al. Controlled formation of highly organized mesoporous titania thin films: From mesostructured hybrids to mesoporous nanoanatase TiO2. Journal of the American Chemical Society 2003; 125(32): 9770–9786.

Shibata H, Ogura T, Mukai T, et al. Direct synthesis of mesoporous titania particles having a crystalline wall. Journal of the American Chemical Society 2005; 127(47): 16396–16397.

Hou K, Tian B, Li F, et al. Highly crystallized mesoporous TiO2 films and their applications in dye sensitized solar cells. Journal of Materials Chemistry 2005; 15(24): 2414–2420.

Yang P, Zhao D, Margolese DI, et al. Generalized syntheses of large-pore mesoporous metal oxides with semicrystalline frameworks. Nature 1998; 396(6707): 152–155.

Yu J, Wang X, Fu X. Pore-wall chemistry and photocatalytic activity of mesoporous titania molecular sieve films. Chemistry of Materials 2004; 16(8): 1523–1530.

Smarsly B, Grosso D, Brezesinski T, et al. Highly crystalline cubic mesoporousTiO2 with 10-nm pore diameter made with a new block copolymer template. Chemistry of Materials 2004; 16(15): 2948–2952.

Liu K, Fu H, Shi K, et al. Preparation of large-pore mesoporous nanocrystalline TiO2 thin films with tailored pore diameters. Journal of Physical Chemistry B 2005; 109(40): 18719–18722.

Tian G, Fu H, Jing L, et al. Preparation and characterization of stable biphase TiO2 photocatalyst with high crystallinity large surface area and enhanced photoactivity. Journal of Physical Chemistry C 2008; 112(8): 3083–3089.

Peng T, Zhao D, Dai K, et al. Synthesis of titanium dioxide nanoparticles with mesoporous anatase wall and high photocatalytic activity. Journal of Physical Chemistry B 2005; 109(11): 4947–4952.

Zhang R, Tu B, Zhao D. Synthesis of highly stable and crystalline mesoporous anatase by using a simple surfactant sulfuric acid carbonization method. Chemistry-A European Journal 2010; 16(33): 9977–9981.

Zhou W, Sun F, Pan K, et al. Well-ordered large-pore mesoporous anatase TiO2 with remarkably high thermal stability and improved crystallinity: Preparation characterization and photocatalytic performance. Advanced Functional Materials 2011; 21(10): 1922–1930.

Wu Z, Li Q, Feng D, et al. Ordered mesoporous crystallineγ-Al2O3 with variable architecture and porosity from a single hard template. Journal of the American Chemical Society 2010; 132(34): 12042–12050.

Yan X, Gottardo L, Bernard S, et al. Ordered mesoporous silicoboron carbonitride materials via preceramic polymer nanocasting. Chemistry of Materials 2008; 20(20): 6325–6334.

Zhu H, Liu Z, Wang Y, et al. Nanosized CaCO3 as hard template for creation of intracrystal pores within silicalite-1crystal. Chemistry of Materials 2008; 20(3): 1134–1139.

Chen Z, Zheng B, Li X, et al. Research progress of nano materials prepared by template method. Chemical Industry and Engineering Progress 2010; 29(1): 94–99.

Yue W, Randorn C, Attidekou PS, et al. Syntheses, Li insertion, and photoactivity of mesoporous crystalline TiO2. Advanced Functional Materials 2009; 19(17): 2826–2833.

Yue W, Xu X, Irvine JTS, et al. Mesoporous monocrystalline TiO2 and its solid-state electrochemical properties. Chemistry of Materials 2009; 21(12): 2540–2546.

Zhang Z, Zuo F, Feng P. Hard template synthesis of crystalline mesoporous anatase TiO2 for photocatalytic hydrogen evolution. Journal of Materials Chemistry 2010; 20(11): 2206–2212.

Ren Y, Hardwick LJ, Bruce PG. Lithium intercalation into mesoporous anatase with an ordered 3D pore structure. Angewandte Chemie International Edition 2010; 49(14): 2570–2574.

Wang K, Wei M, Morris MA, et al. Mesoporous titania nanotubes: Their preparation and application as electrode materials for rechargeable lithium batteries. Advanced Materials 2007; 19(19): 3016–3020.

Gnatyuk Y, Smirnova AN, Kordubanb O, et al. Effect of zirconium incorporation on the stabilization of TiO2 mesoporous structure. Surface and Interface Analysis 2010; 42(6-7): 1276–1280.

Zhou W, Liu K, Fu H, et al. Multi-modal mesoporous TiO2-ZrO2 composites with high photocatalytic activity and hydrophilicity. Nanotechnology 2008; 19(3): 5610.

Zhou W, Fu H, Pan K, et al. Mesoporous TiO2/α-Fe2O3: Bifunctional composites for effective elimination of arsenite contamination through simultaneous photocatalytic oxidation and adsorption. Journal of Physical Chemistry C 2008; 112(49): 19584–19589.

Chen X, Wang X, Fu X.Hierarchical macro/mesoporous TiO2/SiO2 and TiO2/ZrO2 nanocomposites for environmental photocatalysis. Energy Environmental Science 2009; 2: 872–877.

Li G, Zhang D, Yu J. Thermally stable ordered mesoporous CeO2/TiO2 visible-light photocatalysts. Physical Chemistry Chemical Physics 2009; 11(19): 3775–3782.

Jung KY, Jung YR, Jeon JK, et al. Preparation of mesoporous V2O5/TiO2 via spray pyrolysis and its application to the catalytic conversion of 1, 2-dichloro-benzene. Journal of Industrial and Engineering Chemistry 2011; 17(1): 144–148.

Liu J, Sun Q, Fu Y, et al. Preparation and characterization of mesoporous VOx-TiO2 complex oxides for the selective oxidation of methanol to dimethoxymethane. Journal of Colloid and Interface Science 2009; 335(2): 216–221.

Stodolny M, Laniecki M. Synthesis and characterization of mesoporous Ta2O5-TiO2 photocatalysts for water splitting. Catalysis Today 2009; 142(3-4): 314–319.

Zhan S, Yang J, Liu Y, et al. Mesoporous Fe2O3-doped TiO2 nanostructured fibers with higher photo-catalytic activity. Journal of Colloid and Interface Science 2011; 355(2): 328–333.

Cao J, Shao G, Ma TY, et al. Hierarchical meso-macroporous titania-supported CuO nanocatalysts: Preparation characterization and catalytic CO oxidation. Journal of Materials Science 2009; 44(24): 6717–6726.

Cojocariu AM, Mutin PH, Dumitriu E, et al. Mild oxidation of bulky organic compounds with hydrogen peroxide over mesoporous TiO2-SiO2 xerogels prepared by non-hydrolytic sol-gel. Applied Catalysis B: Environmental 2011; 97(3-4): 407–413.

Yao N, Cao S, Yeung KL. Mesoporous TiO2-SiO2 aerogels with hierarchal pore structures. Microporous and Mesoporous Materials 2009; 117: 570–579.

Sahu DR, Hong LY, Wang SC, et al. Synthesis analysis and characterization of ordered mesoporous TiO2/SBA-15 matrix: Effect of calcination temperature. Microporous and Mesoporous Materials 2009; 117(3): 640–649.

He C, Tian B, Zhang J. Thermally stable SiO2-doped mesoporous anatase TiO2 with large surface area and excellent photocatalytic activity. Journal of Colloid and Interface Science 2010; 344(2): 382–389.

Cha MA, Shin C, Kannaiyan D, et al. A versatile approach to the fabrication of TiO2 nanostructures with reverse morphology and mesoporous Ag/TiO2 thin films via cooperative PS-b-PEO self-assembly and a sol-gel process. Journal of Materials Chemistry 2009; 19(39): 7245–7250.

Bian Z, Zhu J, Cao F, et al.In situ encapsulation of Au nanoparticles in mesoporous core-shell TiO2 microspheres with enhanced activity and durability. Chemical Communications 2009; 120(32): 3789–3791.

Zhao J, Sallard S, Smarsly BM, et al. Photocatalytic performances of mesoporous TiO2 films doped with gold clusters. Journal of Materials Chemistry 2010; 20(14): 2831–2839.

Yu J, Yue L, Liu S, et al. Hydrothermal preparation and photocatalytic activity of mesoporous Au-TiO2 nanocomposite microspheres. Journal of Colloid and Interface Science 2009; 334(1): 58–64.

Ismail AA, Bahnemann DW. One-step synthesis of mesoporous platinum/titania nanocomposites as photocatalyst with enhanced photocatalytic activity for methanol oxidation. Green Chemistry 2011; 13: 428–435.

Wu S, He J, Zhou J, et al. Fabrication of unique stripe-shaped mesoporous TiO2 films and their performance as a novel photo-assisted catalyst support for DMFCs. Journal of Materials Chemistry 2011; 21(9): 2852–2854.

Cui F, Hua Z, Wei C, et al. Highly dispersed Au nanoparticles incorporated mesoporous TiO2 thin films with ultrahigh Au content. Journal of Materials Chemistry 2009; 19(31): 7632–7637.

May RA, Patel MN, Johnston KP, et al. Flow-based multiadsorbate ellipsometric porosimetry for the characterization of mesoporous Pt-TiO2 and Au-TiO2 Nanocomposites. Langmuir 2009; 25(8): 4498–4509.

Chu H, Yu C, Wan Y, et al. Synthesis of ordered mesoporous bifunctional TiO2-SiO2-polymer nanocomposites. Journal of Materials Chemistry 2009; 19(45): 8610–8618.

Liu L, Wang G, Li Y, et al. CdSe quantum dot-sensitized Au/TiO2 hybrid mesoporous films and their enhanced photoelectrochemical performance. Nano Research 2011; 4(3): 249–258.

Idakiev VT, Abakova TT, Enchev K, et al. Gold nano particles supported on ceria-modified mesoporous-macroporous binary metal oxides as highly active catalysts for low-temperature water-gas shift reaction. Journal of Materials Science 2009; 44(24): 6637–6643.

Yu D, Liu Y, Wu Z. Low-temperature catalytic oxidation of toluene over mesoporous MnOx-CeO2/TiO2 prepared by sol-gel method. Catalysis Communications 2010; 11(8): 788–791.

Narkhede VV, Toni AD, Narkhede VS, et al. Pt nanoparticles inside the mesopores of TiO2-MCM-48: Synthesis characterization and catalytic activity for CO oxidation. Journal of Materials Science 2009; 44(24): 6701–6709.




DOI: http://dx.doi.org/10.24294/ace.v4i2.1359

Refbacks

  • There are currently no refbacks.


Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

Creative Commons License

This site is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.