Study on photocatalytic properties of Cu2O/TiO2 heterojunction composite films

Hailing Zhu, Yanyan Tang

Article ID: 1352
Vol 4, Issue 2, 2021

VIEWS - 921 (Abstract) 200 (PDF)

Abstract


Cu2O/TiO2 semiconductor heterostructure photocatalytic composite thin films were prepared by the sol-gel method and magnetron sputtering technology. Uniform and transparent TiO2 thin films were prepared by sol dipping and pulling with butyl titanate as the raw material. P-type Cu2O thin films were reactive sputtered on the surface of TiO2 thin films with metal Cu as target source. The catalysts were characterized by SEM, XRD and UV-Vis. The photocatalytic activity of heterojunction composite films under simulated sunlight was investigated by dye degradation experiments, and its mechanism is discussed. The results show that the heterojunction film formed by the composite of TiO2 and Cu2O has good photocatalytic activity under simulated sunlight. The heterojunction composite expands the light response range and light response intensity of the catalyst and improves the quantum efficiency. It is a kind of photocatalytic composite film that makes full use of solar energy.

Keywords


Cu2O/TiO2; Composite Film; Heterojunction; Photocatalysis; Solar Energy

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References


1. Gu G, He Z, Tao Y, et al. Conductivity of nanometer TiO2 thin films by magnetron sputtering. Vacuum 2003; 70(1): l7–20.

2. Meyer K, Zimmermann I. Effect of glidants inbinary powder mixtures. Powder Technology 2004; l39(1): 40–54.

3. Gan Y, Zou C, Yang P, et al. Effect of Au nanoparticle size on photocatalysis performance of Au/TiO2 membrane. Petrochemical Technology 2005; 34(6): 578–581.

4. Mao L, Li Q, Zhang Z. Study on surface states of Pt/TiO2 thin film in different atmospheres. Solar Energy 2007; 81(10): 1280–1284.

5. Kim JC, Choi JK, Lee YB, et al. Enhanced photocatalytic activity in composites of TiO2 nanotubes and CdS nanoparticles. Chemical Communications 2006; (48): 5024–5026.

6. Wang B, Jing L, Qu Y, et al. SPV and PL performances of TiO2 nanoparticles capped with DBS. Chinese Journal of Chemical Physics 2005; 18(5): 807–811.

7. Bessekhouad Y, Robert D, Weber JV. Photocatalytic activity of Cu2O/TiO2, Bi2O3/TiO2 and ZnMn2O4/TiO2 heterojunctions. Catalysis Today 2005; 101(3-4): 315–321.

8. Siripala W, Ivanovskaya A, Jaramillo TF, et al. A Cu2O/TiO2 heterojunction thin film cathode for photoelectrocatalysis. Solar Energy Materials and Solar Cells 2003; 77(3): 229–237.

9. Zhu H, Zhang J, Li C, et al. Cu2O thin films deposited by reactive direct current magnetron puttering. Thin Solid Films 2009; 517(19): 5700–5704.

10. Zhu H. Performance of TiO2 thin films connected with Cu micro-grid. Journal of Weifang University 2011; (6): 41–44.

11. Zhu H. The Cu2O thin films prepared by DC reactive magnetron sputtering. Journal of Weifang University 2010; 10(4): 111–114.

12. Andrew M, George H, Sharan B, et al. Thick titanium dioxide films for semiconductor photocatalysis. Journal of Photochemistry and Photobiology A: Chemistry 2003; 160(3): 185–194.

13. Senevirathna MKI, Pitigala PKDDP, Tennakone K. Water photoreduction with Cu2O quantum dots on TiO2 nano-particles. Journal of Photochemistry and Photobiology A: Chemistry 2005; 171(3): 257–259.

14. Zhang J, Zhu H, Zheng S, et al. TiO2 film/Cu2O microgrid heterojunction with photocatalytic activity under solar light irradiation. ACS Applied Materials & Interfaces 2009; 1(10): 2111–2114.

15. Li S, Luo Y, Ren Q, et al. Study on the preparation of TiO2-Cu2O nano-composite film and its fluorescence properties. Chemistry 2007; (8): 629–632.




DOI: https://doi.org/10.24294/ace.v4i2.1352

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