Synthesis and Structural-chemical Studied of Adduct of Coordination Supramolecular Porous Polymer Hexaaquatribenzene-1,2,4,5- Teacarbonato-tetrairon(iii) with Dipyridyl

B. T. Usubaliyev1, D. B. Taghiyev2, M. K. Munshiyeva2, G. M. Aliyeva2, F. B. Aliyeva2, A. K. Rzayeva1, M. M. Hasanova1, P. S. Safarova1, G. Z. Mammadova2

Abstract


An α, α′-dipyridyl adduct of a complex compound hexaaquatribenzene-1,2,4,5-tetracarbonatotetra iron (III) with porous structure was synthesized for the first time. According to the results of elemental, X-ray, IR-spectroscopic and differential-thermal analyses the individuality, chemical formula, thermal destruction, and form of coordination of acidic anion and dipyridyl were established. During interaction of a complex compound with dipyridyl, it completely loses all crystallization molecule of water resulting in a compound with a chemical formula of Fe4(C6H2(COO)4)3(dpy)2(dipyridyl). Using the identification of diffraction pattern the parameters of lattice cell of the complex compound were determined.

Keywords


Compound; Adduct; Thermal Destruction; Chemical Formula; Crystal Structure

Full Text:

PDF

References


usubaliyev b.t., Shiulin A.N., Mammadov Kh.S. Crystalline and molecular structure of decahydrate complex of copper with 1,2,4,5-benzenetetracarboxylic acid. Coordination chemistry. 1982; 8(11): 1532-1538.

Usubaliyev B.T., Munshiyeva M.K., Nurullayev V.Kh. et al. Synthesis, Physical and Structure-Chemical of Research of Coordinating Compounds of Diaqua-1,2,4,5-Benzoltetracarbonat Dicopper (II). Bull Of Environment, Pharmacology and life sciences. 2016; 5 (3): 12-17.

Usubaliyev B.T., Nurullayev V.Kh., Aliyeva F.B. et al. Synthesis and Structural-Chemical Research of Coordinating compounds of tetraaqua Bisbenzol-1,2,4,5-Tetracarboxylate Dizinc (II). Bull. of Environment, Pharmacology and life sciences 2016; 5 (4): 10-16.

Usubaliyev B.T., Taghiyev D.B., Nurullayev V.Kh. et al. Structural-Chemical Research of Coordination compounds of Hexaaqua-Bis benzol 1,2,4,5-Tetracarbonate Diiron (II) with a layered-porous structure. J. of Nanomaterials and Molecular Nanotechnology 2017; 6 (1): 1-5.

Usubaliyev B.T., Taghiyev D.B., Nurullayev V.Kh. et al. Synthesis, Physical and Structure-Chemical studies of hexaaqua tribenzene-1,2,4,5-tetracarbontetrairon (III) coordination compound. Frontiers in Nanoscience and Nanotechnology, 2017; 3 (2): 4.

Nakamato K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. Moscow: Mir, 1991. 535.

Bellamy L.I. Advances in Infrared group frequencies. Moscow: Mir, 1971. 318.

Najafov G.N., Shnulin A.N.,.Mammadov Kh.S. Crystalline structure of molecular complex di-(p-oxybenzoate) tripyridine-Cd (II) and pyridine. J. of structural chemistry. 1981; 22(3): 106-112.

Najafov G.N., Usubaliyev B.T., Amiraslanov I.R. et al. Crystalline structure of bis-pyridine bis-(p-oxybenzoate) zinc (II) dipyridine. Coordination chemistry 1981; 7(5) 770-775.


Refbacks

  • There are currently no refbacks.


Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

Creative Commons License

This site is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.