Application of X-ray imaging technology in energy materials research
Vol 4, Issue 1, 2021
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Abstract
With the increasing demand for sustainable energy, advanced characterization methods are becoming more and more important in the field of energy materials research. With the help of X-ray imaging technology, we can obtain the morphology, structure and stress change information of energy materials in real time from two-dimensional and three-dimensional perspectives. In addition, with the help of high penetration X-ray and high brightness synchrotron radiation source, in-situ experiments are designed to obtain the qualitative and quantitative change information of samples during the charge and discharge process. In this paper, X-ray imaging technology based on synchrotron and its related applications are reviewed. The applications of several main X-ray imaging technologies in the field of energy materials, including X-ray projection imaging, transmission X-ray microscopy, scanning transmission X-ray microscopy, X-ray fluorescence microscopy and coherent diffraction imaging, are discussed. The application prospects and development directions of X-ray imaging in the future are prospected.
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1. Li W, Li M, Hu Y, et al. Synchrotron-based X-ray absorption fine structures, X-ray diffraction, and X-ray microscopy techniques applied in the study of lithium secondary batteries. Small Methods 2018; 2(8): 1700341.
2. Chen J. High resolution X-ray microscopy and its application [PhD thesis]. Anhui: University of Science and Technology of China; 2010.
3. Yu Z, Wang J, Wang L, et al. Unraveling the origins of the “Unreactive Core” in conversion electrodes to trigger high Sodium-Ion electrochemistry. ACS Energy Letters 2019; 4(8): 2007–2012.
4. Shen F, Dixit M, Xiao X, et al. Effect of pore connectivity on Li dendrite propagation within LLZO electrolytes observed with Synchrotron X-ray tomography. ACS Energy Letters 2018; 3(4): 1056–1061.
5. Shearing PR, Howard LE, Jørgensen PS, et al. Characterization of the 3-dimensional microstructure of a graphite negative electrode from a Li-ion battery. Electrochemistry Communications 2010; 12: 374–377.
6. Waldmann T, Iturrondobeitia A, Kasper M, et al. Review—Post-mortem analysis of aged Lithium-Ion batteries: Disassembly methodology and physico-chemical analysis techniques. Journal of the Electrochem Society 2016; 163(10): A2149–A2164.
7. Zielke L, Hutzenlaub T, Wheeler DR, et al. A combination of X-Ray tomography and carbon binder modeling: Reconstructing the three phases of LiCoO2 Li-Ion battery cathodes. Advanced Energy Materials 2014; 4: 1301617.
8. Ebner M, Chung D, García RE, et al. Tortuosity anisotropy in Lithium-Ion battery electrodes. Advanced Energy Materials 2014; 4(5): 1301278.
9. Schneider A, Wieser C, Roth J, et al. Impact of synchrotron radiation on fuel cell operation in imaging experiments. Journal of Power Sources 2010; 195: 6349–6355.
10. Schneider G. Cryo X-ray microscopy with high spatial resolution in amplitude and phase contrast. Ultramicroscopy 1998; 75(2): 85–104.
11. Wang J, Chen-Wiegart YK, Wang J. In situ three-dimensional synchrotron X-Ray nanotomography of the (De)lithiation processes in Tin Anodes+. Angewandte. Chemie International Edition 2014; 53: 4460–4464.
12. Wang L, Wang J, Zuo P. Probing battery electrochemistry with in operando synchrotron X-Ray imaging techniques. Small Methods 2018; 2(8): 1700293.
13. Wang J, Chen-Wiegart YK, Wang J. In situ chemical mapping of a lithium-ion battery using full-field hard X-ray spectroscopic imaging. Chemical. Communiations 2013; 49(58): 6480–6482.
14. Wang J, Chen-Wiegart YK, Wang J, et al. Visualization of anisotropic-isotropic phase transformation dynamics in battery electrode particles. Nature Communications 2016; 7: 12732.
15. Weker JN, Toney MF. Emerging in situ and operando nanoscale X-Ray imaging techniques for energy storage materials. Advanced Functional Materials 2015; 25: 1622–1637.
16. Wang L. Study of charge and discharge properties for sodium/lithium storage materials via the synchrotron-based techniques [PhD thesis]. Harbin: Harbin Institute of Technology; 2018.
17. Lim J, Li Y, Alsem DH, et al. Origin and hysteresis of lithium compositional spatiodynamics within battery primary particles. Science 2016; 353(6299): 566–571.
18. Yu X, Pan H, Zhou Y, et al. Direct observation of the redistribution of sulfur and polysufides in Li-S batteries during the first cycle by in situ X-Ray fluorescence microscopy. Advanced Energy Materials 2015; 5(16): 1500072.
19. Boesenberg U, Falk M, Ryan CG, et al. Correlation between chemical and morphological heterogeneities in LiNi0.5Mn1.5O4 spinel composite electrodes for Lithium-Ion batteries determined by Micro-X-ray fluorescence analysis. Chemistry of Materials 2015; 27(7): 2525–2531.
20. Xiao T, Xie H, Deng B, et al. Progresses of X-ray imaging methodology and its applications at Shanghai Synchrotron Radiation Facility. Acta Optica Sinica 2014; 34(1): 9–23.
21. Takahashi Y, Nishino Y, Tsutsumi R, et al. High-resolution diffraction microscopy using the plane-wave field of a nearly diffraction limited focused x-ray beam. Physical Review B 2009; 80: 054103.
22. Huang X, Yan H, Nazaretski E, et al. 11 nm hard X-ray focus from a large-aperture multilayer Laue lens. Scientific Reports 2013; 3: 3562.
23. Ulvestad A, Singer A, Cho HM, et al. Single particle nanomechanics in operando batteries via lensless strain mapping. Nano Letters 2014; 14(9): 5123–5127.
24. Rodenberg JM, Hurst AC, Cullis AG, et al. Hard-X-Ray lensless imaging of extended objects. Physical Review Letters 2007; 98(3): 034801.
25. Ma L. X shexian jingtixue de bainian huihuang (Chinese) [A century of glory in X-ray crystallography]. Progress in Physics 2014; 34(2): 47–117.
DOI: https://doi.org/10.24294/irr.v4i1.1737
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