Green synthesis and characterization of iron nanoparticle using extracted bitter guard leaves used as methylene blue removal

Thin Phyu Lin; Kyu Kyu Khaing; Aung Than Htwe; May Thazin Oo; Su Su Soe Nyunt

doi:10.24294/can.v6i1.3183

Green synthesis and characterization of iron nanoparticle using extracted bitter guard leaves used as methylene blue removal

Thin Phyu Lin, Kyu Kyu Khaing, Aung Than Htwe, May Thazin Oo, Su Su Soe Nyunt

Article ID: 3183
Vol 6, Issue 1, 2023

VIEWS - 416 (Abstract) 121 (PDF)

Abstract

Zero-valent iron is a moderately reducing reagent that is both non-toxic and affordable. In the present work, iron nanoparticles were synthesized using bitter guard leaf extract (Momordica charantia L.) (BGL-Fe NP). Using leaf samples from bitter protectant extract, iron nanoparticles were synthesized with secondary metabolites such as flavonoids and polyphenols acting as capping and reducing agents. Polyphenols reduce Fe²⁺/Fe³⁺ to nanovalent iron or iron nanoparticles. Iron nanoparticles were synthesized by reducing iron chloride as a precursor with bitter protective leaf extract in an alkaline environment. The obtained BGL-Fe NPs were calcined for 4 h at various temperatures of 400 °C, 500 °C, and 600 °C. The obtained samples were coded as BGL-Fe NPs-4, BGL-Fe NPs-5, and BGL-Fe NPs-6, respectively. The synthesized BGL-Fe NPs were systematically characterized by XRD, SEM, FTIR, UV-Vis and TG-DTA analysis. The obtained BGL-Fe NPs were then used as an adsorbent to remove the aqueous solution of basic methylene blue (MB) dye. MB concentration was monitored using UV-Vis spectroscopy.

Keywords

Iron Nanoparticle; Characterization; Methylene Blue

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References

1. Hoag GE, Collins JB, Holcomb JL, et al. Degradation of bromothymol blue by ‘greener’nano-scale zero-valent iron synthesized using tea polyphenols. Journal of Materials Chemistry 2009; 19(45): 8671–8677. doi: 10.1039/B909148C.

2. Ghanim D, Al-Kindi GY, Hassan AK. Green synthesis of iron nanoparticles using black tea leaves extract as adsorbent for removing eriochrome blue-black B dye. Engineering and Technology Journal 2020; 38(10): 1558–1569. doi: 10.30684/etj.v38i10A.1225.

3. Prema P, Thangapandian S, Selvarani M, et al. Color removal efficiency of dyes using nanozerovalent iron treatment. Toxicological & Environmental Chemistry 2011; 93(10): 1908–1917. doi: 10.1080/02772248.2011.606613.

4. Tan KB, Vakili M, Horri BA, et al. Adsorption of dyes by nanomaterials: Recent developments and adsorption mechanisms. Separation and Purification Technology 2015; 150: 229–242. doi: 10.1016/j.seppur.2015.07.009.

5. Kuang Y, Wang Q, Chen Z, et al. Heterogeneous fenton-like oxidation of monochlorobenzene using green synthesis of iron nanoparticles. Journal of Colloid and Interface Science 2013; 15(410): 67–73. doi: 10.1016/j.jcis.2013.08.020.

6. Wu Y, Zeng S, Wang F, et al. Heterogeneous Fenton-like oxidation of malachite green by iron-based nanoparticles synthesized by tea extract as a catalyst. Separation and Purification Technology 2015; 154: 161–167. doi: 10.1016/j.seppur.2015.09.022.

7. Sravanthi M, Manjunatha KG. Corrosion studies of as casted and heat treated aluminium-7075 composites. Materials Today: Proceedings 2018; 5(10): 22581–22594. doi: 10.1016/j.matpr.2018.06.632.

8. Bolade OP, Williams AB, Benson NU. Green synthesis of iron-based nanomaterials for environmental remediation: A review. Environmental Nanotechnology, Monitoring & Management 2020; 13: 100279. doi: 10.1016/j.enmm.2019.100279.

9. Gouamid M, Ouahrani MR, Bensaci MB. Adsorption equilibrium, kinetics and thermodynamics of methylene blue from aqueous solutions using date palm leaves. Energy Procedia 2013; 36: 898–907. doi: 10.1016/j.egypro.2013.07.103.

10. Albadarin AB, Collins MN, Naushad M, et al. Activated lignin-chitosan extruded blends for efficient adsorption of methylene blue. Chemical Engineering Journal 2017; 307: 264–272. doi: 10.1016/j.cej.2016.08.089.

11. Sun X, Kurokawa T, Suzuki M, et al. Removal of cationic dye methylene blue by zero-valent iron: Effects of pH and dissolved oxygen on removal mechanisms. Journal of Environmental Science and Health, Part A 2015; 50(10): 1057–1071. doi: 10.1080/10934529.2015.1038181.

12. Khan A, Prabhu SM, Park J, et al. Azo dye decolorization by ZVI under circum-neutral pH conditions and the characterization of ZVI corrosion products. Journal of Industrial and Engineering Chemistry 2017; 47: 86–93. doi: 10.1016/j.jiec.2016.11.017.

13. Fan J, Guo Y, Wang J, et al. Rapid decolorization of azo dye methyl orange in aqueous solution by nanoscale zerovalent iron particles. Journal of Hazardous Materials 2009; 166(2–3): 904–910. doi: 10.1016/j.jhazmat.2008.11.091.

14. Lin Y, Chen Z, Chen Z, et al. Decoloration of acid violet red B by bentonite-supported nanoscale zero-valent iron: Reactivity, characterization, kinetics and reaction pathway. Applied Clay Science 2014; 93–94: 56–61. doi: 10.1016/j.clay.2014.02.020.

15. Bao Y, Zhang G. Study of adsorption characteristics of methylene blue onto activated carbon made by Salix psammophila. Energy Procedia 2012; 16: 1141–1146. doi: 10.1016/j.egypro.2012.01.182.

16. Chen Z, Wang T, Jin X, et al. Multifunctional kaolinite-supported nanoscale zero-valent iron used for the adsorption and degradation of crystal violet in aqueous solution. Journal of Colloid and Interface Science 2013; 398: 59–66. doi: 10.1016/j.jcis.2013.02.020.

17. Hamdy A, Mostafa MK, Nasr M. Zero-valent iron nanoparticles for methylene blue removal from aqueous solutions and textile wastewater treatment, with cost estimation. Water Science and Technology 2018; 78(2): 367–378. doi: 10.2166/wst.2018.306.

DOI: https://doi.org/10.24294/can.v6i1.3183