Synthesis and structural-chemical studies of adduct of coordination supramolecular porous polymer hexaaquatribenzene-1,2,4,5-tetracarbonato-tetrairon(III) with dipyridyl

Usubaliyev Beybala Taji, Taghiyev D. B., Munshiyeva M. K., Aliyeva G. M., Aliyeva F. B., Rzayeva A. K., Hasanova M. M., Safarova P. S., Mammadova G. Z.

Article ID: 894
Vol 4, Issue 1, 2021

VIEWS - 909 (Abstract) 71 (PDF)

Abstract


An α, α′-dipyridyl adduct of a complex compound hexaaquatribenzene-1,2,4,5-tetracarbonatotetra iron (III) with porous structure was synthesized for the first time. According to the results of elemental, X-ray, IR-spectroscopic and differential-thermal analyses the individuality, chemical formula, thermal destruction, and form of coordination of acidic anion and dipyridyl were established. During interaction of a complex compound with dipyridyl, it completely loses all crystallization molecule of water resulting in a compound with a chemical formula of Fe4(C6H2(COO)4)3(dpy)2(dipyridyl). Using the identification of diffraction pattern the parameters of lattice cell of the complex compound were determined.


Keywords


compound; adduct; thermal destruction; chemical formula; crystal structure

Full Text:

PDF


References


1. Usubaliyev BT, Shiulin AN, Mammadov KhS. Crystalline and molecular structure of decahydrate complex of copper with 1,2,4,5-benzene¬tetracarboxylic acid. Coordination chemistry 1982; 8(11): 1532–1538.

2. Usubaliyev BT, Munshiyeva MK, Nurullayev VKh. et al. Synthesis, physical and structure-chemical of research of coordinating compounds of diaqua-1,2,4,5-benzoltetracarbonat dicopper (II). Bull Of Environment, Pharmacology and Life Sciences 2016; 5(3): 12–17.

3. Usubaliyev BT, Nurullayev VKh, Aliyeva FB, et al. Synthesis and structural-chemical research of coordinating compounds of tetraaqua bisbenzol-1,2,4,5-tetracarboxylate dizinc (II). Bull of Environment, Pharmacology and Life Sciences 2016; 5(4): 10–16.

4. Usubaliyev BT, Taghiyev DB, Nurullayev VKh, et al. Structural-chemical research of coordination compounds of hexaaqua-bis benzol 1,2,4,5-tetracarbonate diiron (II) with a layered-porous structure. Journal of Nanomaterials and Molecular Nanotechnology 2017; 6(1): 1–5.

5. Usubaliyev BT, Taghiyev DB, Nurullayev VKh, et al. Synthesis, physical and structure-chemical studies of hexaaqua tribenzene-1,2,4,5-tetracarbontetrairon (III) coordination compound. Frontiers in Nanoscience and Nanotechnology 2017; 3(2): 4. doi: 10.15761/fnn.1000152

6. Nakamato K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. Mir; 1991; p. 535.

7. Bellamy LJ. Advances in Infrared Group Frequencies. Mir; 1971. p. 318.

8. Najafov GN, Shnulin AN, Mammadov KhS. Crystalline structure of molecular complex di-(p-oxybenzoate) tripyridine-Cd (II) and pyridine. Journal of Structural Chemistry 1981; 22(3): 106–112.

9. Najafov GN, Usubaliyev BT, Amiraslanov IR, et al. Crystalline structure of bis-pyridine bis-(p-oxybenzoate) zinc (II) dipyridine. Coordination Chemistry 1981; 7(5): 770–775.




DOI: https://doi.org/10.24294/jpse.v1i2.894

Refbacks

  • There are currently no refbacks.


Copyright (c) 2021 Usubaliyev Beybala Taji, Taghiyev D. B., Munshiyeva M. K., Aliyeva G. M., Aliyeva F. B., Rzayeva A. K., Hasanova M. M., Safarova P. S., Mammadova G. Z.

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

This site is licensed under a Creative Commons Attribution 4.0 International License.