Advances in atom transfer radical polymerization of modified grain

Changqing Cui, Shaofeng Feng, Liqun Zhu

Article ID: 324
Vol 5, Issue 1, 2022

VIEWS - 5347 (Abstract)

Abstract


Atom transfer radical polymerization (ATRP) is a kind of controllable reactive radical polymerization method with potential application value. The modification of graphene oxide (GO) by ATRP reaction can effectively control various graft polymer molecules Chain length and graft density, giving GO different functionality, such as good solvent dispersibility, environmental sensitive stimulus responsiveness, biocompatibility, and the like. In this paper, ATRP reaction and GO surface non-covalent bonding ATRP polymer molecular chain were directly initiated from GO surface immobilization initiator. The ATRP reaction modified GO was reviewed, and the process conditions and research methods of ATRP modification reaction were summarized, as well as pointed out the functional characteristics and application prospect of GO functionalized composites.


Keywords


atom transfer radical polymerization; graphene oxide; modification

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References


Brodie BC. XIII. On the atomic weight of graphite. Philosophical transactions of the Royal Society of London 1859; 149: 249–259. doi: 10.1098/rstl.1859.0013 Staudenmaier L. Method for the preparation of graphitic acid (German). Berichte der deutschen chemischen Gesellschaft 1898; 31(2): 1481–1487. doi: 10.1002/cber.18980310237 Hummers WS, Offeman RE. Preparation of graphitic oxide. Journal of the American Chemical Society 1958; 80(6): 1339–1339. doi: 10.1021/ja01539a017 Mkhoyan KA, Contryman AW, Silcox J, et al. Atomic and electronic structure of graphene-oxide. Nano Letters 2009; 9(3): 1058–1063. doi: 10.1021/nl8034256 Gao W, Alemany LB, Ci L, Ajayan PM. New insights into the structure and reduction of graphite oxide. Nature Chemistry 2009; 1(5): 403–408. doi: 10.1038/nchem.281 Dreyer DR, Park S, Bielawski CW, Ruoff RS. The chemistry of graphene oxide. Chemical Society Reviews 2010; 39(1): 228–240. doi: 10.1039/b917103g Matyjaszewski K, Xia J. Atom transfer radical polymerization. Chemical Reviews 2001; 101(9): 2921–2990. doi: 10.1021/cr940534g Matyjaszewski K, Tsarevsky NV. Nanostructured functional materials prepared by atom transfer radical polymerization. Nature Chemistry 2009; 1(4): 276–288. doi: 10.1038/nchem.257 Paredes JI, Villar-Rodil S, Martínez-Alonso A, Tascon JM. Graphene oxide dispersions in organic solvents. Langmuir 2008; 24(19): 10560–10564. doi: 10.1021/la801744a Lee SH, Dreyer DR, An J, et al. Polymer brushes via controlled, surface‐initiated atom transfer radical polymerization (ATRP) from graphene oxide. Macromolecular Rapid Communications 2010; 31(3): 281–288. doi: 10.1002/marc.200900641 Roghani-Mamaqani H, Haddadi-Asl V. In-plane functionalizing graphene nanolayers with polystyrene by atom transfer radical polymerization: Grafting from hydroxyl groups. Polymer Composites 2013; 35(2): 386–395. doi: 10.1002/pc.22672 Mrlík M, Ilčíková M, Plachý T, et al. Graphene oxide reduction during surface-initiated atom transfer radical polymerization of glycidyl methacrylate: Controlling electro-responsive properties. Chemical Engineering Journal 2016; 283: 717–720. doi: 10.1016/j.cej.2015.08.013 Li GL, Liu G, Li M, et al. Organo- and water-dispersible graphene oxide−polymer nanosheets for organic electronic memory and gold nanocomposites. The Journal of Physical Chemistry C 2010; 114(29): 12742–12748. doi: 10.1021/jp102640s Layek RK, Samanta S, Chatterjee DP, Nandi AK. Physical and mechanical properties of poly(methyl methacrylate) -functionalized graphene/poly(vinylidine fluoride) nanocomposites: Piezoelectric β polymorph formation. Polymer 2010; 51(24): 5846–5856. doi: 10.1016/j.polymer.2010.09.067 Ilčíková M, Mrlík M, Špitalský Z, et al. A tertiary amine in two competitive processes: Reduction of graphene oxide vs. catalysis of atom transfer radical polymerization. RSC Advances 2015; 5(5): 3370–3376. doi: 10.1039/c4ra12915f Qi K, Sun Y, Duan H, Guo X. A corrosion-protective coating based on a solution-processable polymer-grafted graphene oxide nanocomposite. Corrosion Science 2015; 98: 500–506. doi: 10.1016/j.corsci.2015.05.056 Roghani-Mamaqani H. Surface-initiated ATRP of styrene from epoxy groups of graphene nanolayers: Twofold polystyrene chains and various graft densities. Rsc Advances 2015; 5(66): 53357–53368. doi: 10.1039/C5RA06872J Veca LM, Lu F, Meziani MJ, et al. Polymer functionalization and solubilization of carbon nanosheets. Chemical Communications 2009; 18: 2565. doi: 10.1039/b900590k Nikdel M, Salami-Kalajahi M, Hosseini MS. Dual thermo- and pH-sensitive poly(2-hydroxyethyl methacrylate-co-acrylic acid)-grafted graphene oxide. Colloid and Polymer Science 2014; 292(10): 2599–2610. doi: 10.1007/s00396-014-3313-x Gonçalves G, Marques PAAP, Barros-Timmons A, et al. Graphene oxide modified with PMMA via ATRP as a reinforcement filler. Journal of Materials Chemistry 2010; 20(44): 9927. doi: 10.1039/c0jm01674h Kavitha T, Kang IK, Park SY. Poly(N-vinyl caprolactam) grown on nanographene oxide as an effective nanocargo for drug delivery. Colloids and Surfaces B: Biointerfaces 2014; 115: 37–45. doi: 10.1016/j.colsurfb.2013.11.022 Yang Y, Wang J, Zhang J, et al. Exfoliated graphite oxide decorated by PDMAEMA chains and polymer particles. Langmuir 2009; 25(19): 11808–11814. doi: 10.1021/la901441p Roghani‐Mamaqani H, Haddadi‐Asl V, Khezri K, Salami‐Kalajahi M. Edge‐functionalized graphene nanoplatelets with polystyrene by atom transfer radical polymerization: Grafting through carboxyl groups. Polymer International 2014; 63(11): 1912–1923. doi: 10.1002/pi.4730 Peng K, Wang K, Hsu K, Liu Y. Building up polymer architectures on graphene oxide sheet surfaces through sequential atom transfer radical polymerization. Journal of Polymer Science Part A: Polymer Chemistry 2014; 52(11): 1588–1596. doi: 10.1002/pola.27154 Bak JM, Lee T, Seo E, et al. Thermoresponsive graphene nanosheets by functionalization with polymer brushes. Polymer 2012; 53(2): 316–323. doi: 10.1016/j.polymer.2011.11.057 Bak JM, Lee H. pH-tunable aqueous dispersion of graphene nanocomposites functionalized with poly(acrylic acid) brushes. Polymer 2012; 53(22): 4955–4960. doi: 10.1016/j.polymer.2012.09.005 Fang M, Wang K, Lu H, et al. Single-layer graphene nanosheets with controlled grafting of polymer chains. Journal of Materials Chemistry 2010; 20(10): 1982. doi: 10.1039/b919078c Xu LQ, Wang L, Zhang B, et al. Functionalization of reduced graphene oxide nanosheets via stacking interactions with the fluorescent and water-soluble perylene bisimide-containing polymers. Polymer 2011; 52(11): 2376–2383. doi: 10.1016/j.polymer.2011.03.054 Song S, Wan C, Zhang Y. Non-covalent functionalization of graphene oxide by pyrene-block copolymers for enhancing physical properties of poly(methyl methacrylate). RSC Advances 2015; 5(97): 79947–79955. doi: 10.1039/c5ra14967c Layek RK, Nandi AK. A review on synthesis and properties of polymer functionalized graphene. Polymer 2013; 54(19): 5087–5103. doi: 10.1016/j.polymer.2013.06.027



DOI: https://doi.org/10.24294/jpse.v5i1.324

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