Effect of heating and resistance on emission properties of carbon nanotubes

Sergey V. Bulyarskiy, Alexander A. Dudin, Alexander V. Lakalin, Andrey P. Orlov, Alexander A. Pavlov, Roman M. Ryazanov, Artemiy A. Shamanaev

Article ID: 567
Vol 3, Issue 2, 2020

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Abstract


We have studied the effect of the series resistance on the heating of the cathode, which is based on carbon nanotubes and serves to realize the field emission of electrons into the vacuum. The experiment was performed with the single multi-walled carbon nanotube (MCNT) that was separated from the array grown by CVD method with thin-film Ni-Ti catalyst (nickel 4 nm/Ti 10 nm). The heating of the cathode leads to the appearance of a current of the thermionic emission. The experimental voltage current characteristic exhibited the negative resistance region caused by thermal field emission. This current increases strongly with increasing voltage and contributes to the degradation of the cold emitter. The calculation of the temperature of the end of the cathode is made taking into account the effect of the phenomenon that warms up and cools the cathode. We have developed a method for processing of the emission volt-ampere characteristics of a cathode, which relies on a numerical calculation of the field emission current and the comparison of these calculations with experiments. The model of the volt-ampere characteristic takes into account the CNT’s geometry, properties, its contact with the catalyst, heating and simultaneous implementation of the thermionic and field emission. The calculation made it possible to determine a number of important parameters, including the voltage and current of the beginning of thermionic emission, the temperature distribution along the cathode and the resistance of the nanotube. The phenomenon of thermionic emission from CNTs was investigated experimentally and theoretically. The conditions of this type emission occurrence were defined. The results of the study could form the basis of theory of CNT emitter’s degradation.


Keywords


Carbon Nanotubes; Field Emission; Thermionic Emission; Volt-ampere Characteristic; Emitter Temperature

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References


1. Bulyarskiy SV. Carbon nanotubes: Technology (in Russian). Manage properties application. Ulyanovsk: Strezhen; 2011. p.479.

2. Chernozatonskii LA, Gulyaev YV, Kosakovskaja ZJ, et al. Electron field emission from nanofilament carbon films. Chemical Physics Letters 1995; 233(1-2): 63–68.

3. De Heer WA, Chatelain A, Ugarte D. A carbon nanotube field-emission electron source. Science 1995; 270: 1179–1180.

4. Rinzler AG, Hafner JH, Nikolaev P, et al. Unraveling nanotubes: Field emission from an atomic wire. Science 1995; 269: 1550–1553.

5. Wang Q, Yan M, Chang R. Flat panel display prototype using gated carbon nanotube field emitters. Applied Physics Letters 2001; 78: 1294–1296.

6. Mauger M, Vu TV. Vertically aligned carbon nano-tube arrays for giant field emission displays. Journal of Vacuum Science & Technology B Microelectronics & Nanometer Structures 2006; 24(2): 997–1003.

7.

8. Reyes-Mena A, Jensen CH, Bard E, et al. Miniature X-ray tubes utilizing carbon-nanotube based cold cathodes. Advances in X-ray Analysis 2005; 48: 204–209.

9. Matsumoto T, Mimura H. Point X-ray source using graphite nanofibers and its application to X-ray radiography. Applied Physics Letters 2003; 82: 1637–1639.

10. Saito Y, Uemura S, Hamaguchi K. Cathode ray tube lighting elements with carbon nanotube field emitters. Japanese Journal of Applied Physics 1998; 37(3B): L346–L348.

11. Croci M, Arfaoui I, Stöckli T, et al. A fully sealed luminescent tube based on carbon nanotube field emission. Microelectronics Journal 2004; 35: 329–336.

12. Yasutomo Y, Ohue W, Gotoh Y, et al. Frequency mixing with a tetrode vacuum transistor. IEEE, 2012.

13. Sabaut L, Ponard P, Mazellier JP, et al. Electrostatic modeling of an in-plane gated field emission cath-ode. Journal of Vacuum Science & Technology B 2016; 34(2): 02G101.

14. Yuan X, Zhu W, Zhang Y, et al. A Fully-sealed carbon-nanotube cold-cathode terahertz gyrotron. Scientific Reports 6. 2016. Article number: 32936.

15. Paoloni C, Carlo A, Brunetti F, et al. Design and Fabrication of a 1 THz Backward Wave Amplifier. Terahertz Science and Technology 2011; 4: 1102–1110.

16. Rupesinghe NL, Chhowalla M, Teo KBK, et al. Field emission vacuum power switch using vertically aligned carbon nanotubes. Journal of Vacuum Science & Technology B 2003; 21(1): 1071–1076.

17. Eletskii AV. Carbon nanotube-based electron field emitters. Uspekhi Fizicheskih Nauk 2010; 180(9): 897.

18. Bocharov GS, Eletskii AV. Theory of carbon nano-tube (CNT)-based electron field emitters. Nano-materials 2013; 3: 393–442.

19. Murphy EL, Good RH. Thermionic emission, field emission, and the transition region. Physical Review 1956; 102: 1464–1473.

20. Mayer A, Lambin Ph. Quantum-mechanical simulations of field emission from carbon nanotubes. Carbon 2002; 40: 429–436.

21. Sun J, Zhang Z, Hou S, et al. Work function of single-walled carbon nanotubes determined by field emission microscopy. Applied Physics A 2002; 75(4): 479–483.

22. Vincent P, Purcell ST, Journe C, et al. Modelization of resistive heating of carbon nanotubes during field emission. Physical Review B 2002; 66(7): 429–436.

23. Banerjee PK, Butterfield R. Boundary element methods in engineering science. London: McGRAW-HILL Book Company (UK) Limited; 1981. p.452.

24. Brebbia CA, Telles JCF, Wrobel LC. Boundary element techniques. Berlin, Heidelberg, New York, Tokyo: Springer-verlag; 1984. p.464.

25. Shoup TE. Applied numerical methods for micro-computers. Englewood Cliffs,NJ: Prentice-Hall; 1984. p.194.

26. Bocharov GS, Eletskii AV. Thermal instability of field emission from carbon nanotubes. Technical Physics 2007; 52(4): 498–503.

27. Bocharov GS, Eletskii AV, Sommerer TJ. Optimization of the parameters of a carbon nanotube-based field-emission cathode. Technical Physics 2011; 56(4): 540–545.

28. Ziman JM. Electrons and phonons. The theory of transport phenomena in solids. Oxford at the Clarendon Press; 1960. p.554.

29. Hone J, Llaguno MC, Biercuk MJ, et al. Thermal properties of carbon nanotubes and nanotube-based materials. Applied Physics A 2002; 74: 339–343.

30. Paulini J, Klein T, Simon G. Thermo-field emission and the Nottingham effect. Journal of Physics D: Applied Physics 1993 (Printed in the UK); 26: 1310–1315.

31. Wei W, Liu Y, Wei Y, et al. Tip cooling effect and failure mechanism of field-emitting carbon nano-tubes. Nano Letters 2007; 7: 64–68.

32. Huang N, Chen J, Chen J, et al. Mechanism responsible for initiating carbon nanotube vacuum break-down. Physics Review Letter 2004; 93: 075501.




DOI: https://doi.org/10.24294/can.v3i2.567

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