Advances in Atom Transfer Radical Polymerization of Modified Grain

Changqing Cui, Shaofeng Feng, Liqun Zhu

Abstract


Atom transfer radical polymerization (ATRP) is a kind of controllable reactive radical polymerization method with potential application value. The modification of graphene oxide (GO) by ATRP reaction can effectively control various graft polymer molecules Chain length and graft density, giving GO different functionality, such as good solvent dispersibility, environmental sensitive stimulus responsiveness, biocompatibility, and the like. In this paper, ATRP reaction and GO surface non-covalent bonding ATRP polymer molecular chain were directly initiated from GO surface immobilization initiator. The ATRP reaction modified GO was reviewed, and the process conditions and research methods of ATRP modification reaction were summarized, as well as pointed out the functional characteristics and application prospect of GO functionalized composites.


Full Text:

PDF

References


Brodie B C. On the atomic weight of graphite [J]. Philos. Trans.R. Soc. London, 1859, 149: 249-259.

Staudenmaier L. Method for the preparation of graphitic acid [J]. Berichte der Deutschen Chemischen Gesellschaft, 1898, 31:1481-1487.

Hummers W S, Offeman R E. Preparation of graphitic oxide [J].J. Am. Chem. Soc. , 1958, 80: 1339.

Mkhoyan K A, Contryman A W, Silcox J, et al. Atomic and electronic Structure of graphene-oxide [J]. Nano Lett. , 2009,9:1058-1063.

Gao W, Alemany L B, Ci L J, et al. New insights into the structure and reduction of graphite oxide [J]. Nat. Chem. , 2009,1:403-408.

Dreyer D R, Park S, Bielawski C W, et al. The chemistry of graphene Oxide [J]. Chem. Soc. Rev., 2010, 39: 228-240.

Krzysztof M, Xia J H. Atom transfer radical polymerization [J] Chem. Rev., 2001, 101: 2921-2990.

Matyjaszewski K, Tsarevsky N V. Nanostructured functional Materials prepared by atom transfer radical polymerization [J]. Nat. Chem., 2009,1: 276-288.

Paredes J I, Villar-Rodil S, Martínez-Alonso A, et al. Graphene Oxide dispersions in organic solvents [J]. Langmuir, 2008, 24:10560-10564.

Lee S H, Daniel R D, An J, et al. Polymer brushes via controlled, Surface-initiated atom transfer radical polymerization (ATRP) from graphene oxide. [J]. Macromol. Rapid Commun ,2010, 31: 281-288.

Hossein R M, Vahid H A. In-plane functionalizing graphene Nanolayers with polystyrene by atom radical waste polymerization:Grafting from hydroxyl groups [J]. Polym. Compos.,2014, 35: 386-395.

Mrlík M, IlcíkováM, Plach T, et al. Graphene oxide reduction During surface-initiated atom transfer radical polymerization Of glycidyl methacrylate: measures electro-responsive properties[J]. Chem. Eng. J. , 2016, 283: 717-720.

Li G L, Liu G, Li M, et al. Organo-and water-dispersible Graphene oxide-polymer nanosheets for organic electronic memory and gold nanocomposites [J]. J. Phys. Chem. C, 2010,114:12742-12748.

Layek R K, Samanta S, Chatterjee D P, et al. Physical and Mechanical properties of poly (methyl methacrylate) -functionalized Graphene / poly (vinylidine fluoride) nanocomposites: piezoelectric? Polymorph Formation [J]. Polymer, 2010, 51: 5846-5856.

IlcíkováM, Mrlík M, Spitalsk Z, et al. A tertiary amine in Two competing processes: reduction of graphene oxide vs. Catalysis Of atom transfer radical polymerization [J]. RSC Adv., 2015, 5: 3370-3376.

Qi K, Sun Y M, Duana H W, et al. A corrosion-protective Coating based on a solution-processable polymer-grafted graphene Oxide nanocomposite [J]. Corros. Sci., 2015, 98: 500-506.

Hossein R M. Surface-initiated ATRP of styrene from epoxy Groups of graphene nanolayers: twofold polystyrene chains and

various graft densities [J]. RSC Adv. , 2015, 5: 53357-53368.

Veca L M, Lu F, Meziani M J, et al. Polymer functionalization and solubilization of carbon nanosheets [J]. Chem. Commun ,2009, 18: 2565-2567.

Masoumeh N, Mehdi S K, Mahdi S H. Dual thermo-and pHsensitive Poly (2-hydroxyethyl methacrylate-co-acrylic acid) Grafted Graphene oxide [J]. Colloid Polym. Sci., 2014, 292: 2599-2610.

Gil G, Paula A A P M, Ana B T, et al. Graphene oxide modified With PMMA via ATRP as a reinforcement filler [J]. J. Mater. Chem., 2010, 20: 9927-9934.

Kavitha T, Kang I K, Park Y S. Poly (N-vinyl caprolactam) grown on nanographene oxide as an effective nanocargo for drug Delivery [J]. Colloids Surf. , B, 2014, 115: 37-45.

Yang Y F, Wang J, Zhang J, et al. Exfoliated graphite oxide By PDMAEMA chains and polymer particles [J].Langmuir, 2009, 25: 11808-11814.

Hossein R M, Vahid H A, Khezrollah K, et al. Edgefunctionalized Graphene nanoplatelets with polystyrene by atom Transfer radical polymerization Groups [J]. Polym. Int., 2014, 63: 1912-1923.

Peng K J, Wang K H, Hsu K Y, et al. Building up polymer architectures on graphene oxide sheet surfaces through sequential Atom transfer radical polymerization [J]. J. Polym. Sci. Part A: Polym. Chem., 2014, 52: 1588-1596.

Bak J M, Lee T, Seo E, et al. Thermoresponsive graphene Nanosheets by functionalization with polymer brushes [J]. Polymer, 2012, 53: 316-323.

Bak J M, Lee H. PH-tunable aqueous dispersion of graphene Nanocomposites functionalized with poly (acrylic acid) brushes [J]. Polymer, 2012, 53: 4955-4960.

Fang M, Wang K G, Lu H B, et al. Single-layer graphene Nanosheets with controlled grafting of polymer chains [J]. J. Mater. Chem., 2010, 20: 1982-1992.

Xu L Q, Wang L, Zhang B, et al. Functionalization of reduced Graphene oxide nanosheets via stacking interactions with the fluorescent and water-soluble perylene bisimide-containing polymers[J]. Polymer, 2011, 52: 2376-2383.

Song S Q, Wan C Y, Zhang Y. Non-covalent functionalization of graphene oxide by pyrene-block stocks for enhancing Physical properties of poly (methyl methacrylate [J] .RSC Adv. 2015, 5: 79947-79955.

Rama K L, Arun K N. A review on production and properties of polymer functionalized graphene [J] Polymer, 2013, 54: 5087-5103.




DOI: http://dx.doi.org/10.24294/jpse.v1i1.324

Refbacks

  • There are currently no refbacks.




Creative Commons License

This site is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.