Research Progress of Low Dielectric Benzoxazine Resin

Qiuping Yin, Zhenbo Zhang, Hongyu Liu


Benzoxazine resin, a new type of phenolic resin, has many advantages such as strong molecular design, no small molecular release in the curing process, excellent thermal stability and mechanical properties, and high residual carbon ratio. Thus, it is important for electronic communication industry matrix material. To meet the needs of high-frequency and high -speed communication technology for low-dielectric polymer resin, the low dielectric modification of benzoxazine resin is of great significance to the high frequency and high speed propagation of the signal, which causes a wide range of materials researcher’s attention. In this paper, we reviewed a series of studies on the low dielectric modification of benzoxazine resin in recent years, including the synthesis of new monomers, inorganic - organic hybridization, copolymerization with other resins, and low molecular weight benzoxazine Resin research trends were outlined.

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Rimdusit S, Ishida H. Development of new class of electronic Packaging materials based on ternary systems of benzoxazine, epoxy,And phenolic resins [J]. Polymer, 2000, 22: 7941-7949.

Rimdusit S, Ishida H. Gelation study of high processability and High reliability ternary systems based on benzoxazine, epoxy and Phenolic resins for application electronic packaging materials [J].Rheol. Acta, 2000, 41: 1-9.

Ogura I. Handbook of low and high dielectric constant materials And their applications [M]. Boston: Academic Press, 1999: 213-219.

Hamerton I, Howlin B J, Mitchelll A L, et al. Systematic Examination of thermal, mechanical and dielectrical properties of Aromatic polybenzoxazines [J]. React. Funct. Polym. , 2012, 72:736-744.

[Sua Y C, Chen W C, Ou K L, et al. Study of the morphologies And dielectric constants of nanoporous materials derived from Benzoxazine-terminated poly (3-caprolactone)/polybenzoxazine stocks[J]. Polymer, 2005, 46: 3758-3766.

Kumar R S, Padmanathanbc N, Alagar M. Design of hydrophobic Polydimethylsiloxane and polybenzoxazine hybrids for interlayer Low k dielectrics [J]. New J. Chem. , 2015, 39: 3995-4008.

Zhang K, Zhuang Q X, Liu X Y, et al. Preparation and properties Of novel low dielectric constant benzoxazole-based polybenzoxazine[J]. Polym. Chem. , 2012, 50: 5115-5123.

Zhang K, Zhuang Q X, Cai R L, et al. Synthesis and Copolymerization of benzoxazines with low-solar constants and High thermal stability [J]. RSC Adv. , 2013, 3: 5261-5270.

Herrera P V, Doyama K, Abe H, et al. Synthesis and Characterization of highly fluorinated polymer with the benzoxazine Moiety in the main chain [J] Macromolecules, 2008, 41:9704-9714.

Herrera P V, Ishida H. Synthesis and characterization of highly Fluorinated diamines and benzoxazines derived therefrom

[J]. J. Fluorine Chem. , 2009, 130: 573-580. [11] Parveen A S, Thirukumaran P, Sarojadevi M. Low dielectric Materials from fluorinated polybenzoxazines [J]. Polym. Adv. Technol. , 2014, 25: 1538-1545.

Su Y C, Chang F C. Synthesis and characterization of fluorinated Polybenzoxazine material with low dielectric constant [J]. Polymer, 2003, 44: 7989-7996.

Shieh J Y, Lin C Y, Huang C L, et al. Synthesis and Characterization of novel dihydrobenzoxazineous [J]. J. Appl. Polym. Sci. , 2006, 101: 342-347.

Hwang H J, Lin C Y, Wang C S Flame retardancy and dielectric Properties of dicyclopentadiene-based benzoxazine cured with A phosphorus-containing phenolic resin [J]. J. Appl. Polym.Sci. , 2008, 110: 2413-2423.

Liu Zhihua, Yuan Chuanlong, Huang Faorong. Benzoxazine Blend Resin and Its Glass Fiber Cloth Preparation and properties of reinforced composites [J]. Polymer materials science and engineering, 2013, 30 (4): 13-21.

Xiao Liqun, Yu Ruobing, Zhao Wei, and so on. Benzoxazine resin based aromatic sulfonamide fiber and glass Study on the properties of fiber composites [J]. FRP/Composites, 2010 (6): 21-24.

Wang Y Q, Kou K C, Zhuo L H, et al. Preparation of Boz/Glass fibers/cyanate ester resins lamin composites [J].Polym. Compos. 2015: 1-5.

Li G Z, Wang L C, Ni H L, et al. Polyhedral oligomeric Silsesquioxane (POSS) polymers and copolymers: a review [J].J. Inorg.

Org. Polym., 2001, 3: 123-154.

Tseng M C, Liu Y L. Preparation, morphology, and ultra-low Natural constants of benzoxazine-based polymers/polyhedral Oligomeric silsesquioxane (POSS) nanocomposites [J]. Polymer,2010, 51: 5567-5575.

Vengatesan M R, Devaraju S, Kumar A A, et al. Studies on Thermal and dielectric properties of octa (maleimido phenyl) silsesquioxane (OMPS) Polybenzoxazine (PBZ) hybrid nanocomposites

[J]. High Perform. Polym., 2011, 23: 441-456.

Vengatesan M R, Devaraju S, Dinakaran K, et al. Studies on Thermal and dielectric properties of organo clay and octakis (dim ethylsiloxypropylglycidylether) Silsesquioxane filled polybenzoxazine Hybrid nanocomposites [J]. Polym. Compos. , 2011,11: 1701-1711.

Kumar R S, Alagar M. Dielectric and thermal behaviors of POSS terms polyurethane based polybenzoxazine nanocomposites [J]. RSC Adv., 2015, 42: 33008-33015.

Sethuraman K, Vengatesan M R, Lakshmikandhan T, et al. Thermal and dielectric properties of 'thiolene' photocured hybrid Composite materials from allylterminated benzoxazine and SH-POSS [J]. High Perform. Polym., 2015, 27: 1-12.

Thirukumaran P, Parveen A S, Sarojadevi M. Synthesis of Eugenol-based polybenzoxazine-poss nanocomposites for low dielectric Applications [J]. Polym. Compos. , 2015, 11: 1973-1982.

Chandramohan A, Chozhan C K, Alagar M. Polysilsesquioxanere inforced Phosphorous containing bis (4-maleimidophenyl) Benzoxazine hybrid nanocomposites [J]. High Perform. Polym., 2013, 25: 744-758.

Liu H C, Su W C, Liu Y L. Self-assembled benzoxazine-bridged Polysilsesquioxanes exhibiting ultralow-host constants and Yellow-light photoluminescent emission [J]. J. Mater. Chem., 2011,21: 7182-7187.

Kumar R S, Ariraman M, Alagar M. Design of lamellar structured POSS / BPZ polybenzoxazine nanocomposites as the novel Class of ultra low k dielectric material [J]. RSC Adv., 2014, 4:19127-19136.

Zhang K, Zhuang Q Z, Liu X Y, et al. A new benzoxazine Containing benzoxazole-functionalized polyhedral oligomeric silsesquioxane And the corresponding polybenzoxazine nanocomposites[J]. Macromolecules, 2013, 46: 2696-2704.

[Kumar R S, Ariraman M, Alagar M. Studies on MCM-41/PDMS based hybrid polybenzoxazine nanocomposites for interlayer Low k dielectrics [J]. RSC Adv. , 2015, 5: 40798-40806.

Vengatesan M R, Devaraju S, Dinakaran K, et al. SBA-15 filled Polybenzoxazine nanocomposites for low-k dielectric applications[J]. J. Mater. Chem. , 2012, 22: 7559-7566.

Selvaraj V, Jayanthi K P, Lakshmikandhanc T, et al. Development of a polybenzoxazine/TSBA-15composite from the Renewable resource cardanol for low-k applications [J]. RSC

Adv. , 2015, 5: 48898-48907.

Geim A K. Graphene: status and prospects [J]. Science, 2009,324: 1530-1534.

Stankovich S, Dikin D A, Dommett G H B, et al. Graphenebased Composite materials [J]. Nature, 2006, 442: 282-286. [34]

Novoselov K S, Falko V I, Colombo L, et al. A roadmap for Graphene [J]. Nature, 2012,490: 192-200.

Zeng M, Wang J, Li R R, et al. The curing behavior and thermal Property of graphene oxide/benzoxazine nanocomposites [J]. Polymer, 2013, 54: 3107-3116.

Xu Q Y, Zeng M, Feng Z J, et al. Understanding the effects of carboxylated groups of functionalized graphene oxide on the curing Behavior and intermolecular interactions of benzoxazine Nanocomposites [J]. RSC Adv. , 2016, 6: 31484-31496.

Kumar R S, Ariraman M, Alagar M. Studies on dielectric Properties of GO reinforced bisphenol-Z polybenzoxazine hybrids[J]. RSC Adv. 2015, 5: 23787-23797.

Lin C H, Huang S J, Wang P J, et al. Miscibility, Microstructure, and thermal and dielectric properties of reactive Blends of dicyanate ester and diamine-based benzoxazine [J].Macromolecules, 2012,45: 7461-7466.

Yan H X, Li T T, Feng S, et al. Mechanical and dielectric Properties of blends of dicyanate ester and bisphenol A-based benzoxazine [J]. High Perform. Polym. , 2014, 26: 618-625.

Li Xiaodan, Luo Xiaoyong, Xia Yixing, et al. Benzoxazine/cyanate ester copolymer and performance [J]. Polymer Materials Science and Engineering, 2015,31 (8): 96-101.

Lin C H, Huang C M, Wong T I, et al. High-Tg and lowdielectric Epoxy hotosets based on a propargyl ether-containing Phosphinated benzoxazine [J]. Polym. Chem. , 2014, 52: 1359-


Krishnadevi K, Selvaraj V. Development of halogen-free flame Retardant phosphazene and rice husk ash incorporated benzoxazine Blended epoxy composites for microelectronic applications[J]. New J. Chem. , 2015, 39: 6555-6567.

Krishnadevi K, Grace A N, Alagar M, et al. Development of Hexa (aminophenyl) cyclotriphosphazene-modified cyanate ester Composites for high temperature applications [J]. High Perform. Polym. , 2014, 26: 89-96.

Krishnadevi K, Selvaraj V, Prasanna D. Thermal, mechanical And antibacterial properties of cyclophosphazined incorporated Benzoxazine blended bismaleimide composites [J]. RSC Adv. ,2015, 5: 913-921.

Wang C F, Su Y C, Kuo S W, et al. Low-surface-free-energy Materials based on polybenzoxazines [J]. Angew. Chem. Int. Ed. , 2006, 45: 2248-2251.

Li X D, Xia Y Q, Xu W L, et al. The curing procedure for a Benzoxazine-cyanate-epoxy system and the properties of the terpolymer[J]. Polym. Chem. , 2012, 3: 1629-1633.

Jamshidi S, Yeganeh H, Ataei S M. Preparation and properties of one-pack polybenzoxazine-modified polyurethanes with improved Thermal stability and electrical insulating properties [J]. Polym. Int. , 2011, 60: 126-135.

Gaina C, Ursache O, Gaina V, et al. Poly (urethane-benzoxazine)S [J]. J. Polym. Res. , 2014, 21: 586-596.

Wang Y Q, Kou K C, Zhuo L H, et al. Thermal, mechanical And dielectric properties of BMI modified by the bis allyl benzoxazine[J]. J. Polym. Res. , 2015, 22: 51-59.

Wang Y Q, Kou K C, Zhao W, et al. The effect of functionalized Benzoxazine with allyl groups on the dielectric, mechanical and thermal properties of BMI/BADCy composites [J]. RSC Adv. , 2015, 5: 99313-99321.

Wang Y Q, Kou K C, Wu G L, et al. The effect of bis allyl Benzoxazine on the thermal, mechanical and dielectric properties Of bismaleimide-cyanate blend polymers [J]. RSC Adv. , 2015,5: 58821-58831.

Zhang C X, Luo X X, Zhu R Q, et al. Thermal and dielectric Properties of epoxy/DDS/CTBN adhesive modified by cardanol based Benzoxazine [J]. J. Adhes. Sci. Technol. , 2015, 29:767-777.


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